Resolution MEPC.177(58)
AMENDMENTS TO THE TECHNICAL CODE ON CONTROL OF EMISSION OF NITROGEN OXIDES FROM
MARINE DIESEL ENGINES (NOX TECHNICAL CODE 2008)
(Adopted
on 10 October 2008)
THE
MARINE ENVIRONMENT PROTECTION COMMITTEE,
RECALLING
Article 38(a) of the Convention on the International Maritime Organization
concerning the functions of the Marine Environment Protection Committee (the
Committee) conferred upon it by international conventions for the prevention
and control of marine pollution,
NOTING
article 16 of the International Convention for the Prevention of Pollution from
Ships, 1973 (hereinafter referred to as the "1973 Convention"),
article VI of the Protocol of 1978 relating to the International Convention for
the Prevention of Pollution from Ships, 1973 (hereinafter referred to as the
"1978 Protocol") and article 4 of the Protocol of 1997 to amend the
International Convention for the Prevention of Pollution from Ships, 1973, as
modified by the Protocol of 1978 relating thereto (herein after referred to as
the "1997 Protocol"), which together specify the amendment procedure
of the 1997 Protocol and confer upon the appropriate body of the Organization
the function of considering and adopting amendments to the 1973 Convention, as
modified by the 1978 and 1997 Protocols,
NOTING
ALSO that, by the 1997 Protocol, Annex VI entitled Regulations for the
Prevention of Air Pollution from Ships is added to the 1973 Convention
(hereinafter referred to as "Annex VI"),
NOTING
FURTHER regulation 13 of MARPOL Annex VI which makes the Technical Code on
Control of Emission of Nitrogen Oxides from Marine Diesel Engines (NOx
Technical Code) mandatory under that Annex,
HAVING
CONSIDERED the draft amendments to the NOx Technical Code,
1.
ADOPTS, in accordance with article 16(2)(d) of the 1973 Convention, the
amendments to the NOx Technical Code, as set out at annex to the
present resolution;
2.
DETERMINES, in accordance with article 16(2)(f)(iii) of the 1973 Convention,
that the amendments shall be deemed to have been accepted on 1 January 2010,
unless prior to that date, not less than one-third of the Parties or Parties
the combined merchant fleets of which constitute not less than 50 per cent of
the gross tonnage of the world's merchant fleet, have communicated to the
Organization their objection to the amendments;
3.
INVITES the Parties to note that, in accordance with article 16(2)(g)(ii) of
the 1973 Convention, the said amendments shall enter into force on 1 July 2010
upon their acceptance in accordance with paragraph 2 above;
4.
REQUESTS the Secretary-General, in conformity with article 16(2)(e) of the 1973
Convention, to transmit to all Parties to the 1973 Convention, as modified by
the 1978 and 1997 Protocols, certified copies of the present resolution and the
text of the amendments contained in the Annex;
5.
REQUESTS FURTHER the Secretary-General to transmit to the Members of the
Organization which are not Parties to the 1973 Convention, as modified by the
1978 and 1997 Protocols, copies of the present resolution and its Annex;
6.
INVITES the Parties to MARPOL Annex VI and other Member Governments to bring
the amendments to the NOx Technical Code to the attention of
shipowners, ship operators, shipbuilders, marine diesel engine manufacturers
and any other interested groups.
Technical Code on Control of
Emission of Nitrogen Oxides from Marine Diesel Engines
On
26 September 1997, the Conference of Parties to the International Convention
for the Prevention of Pollution from Ships, 1973, as modified by the Protocol
of 1978 relating thereto (MARPOL 73/78) adopted, by Conference resolution 2,
the Technical Code on Control of Emission of Nitrogen Oxides from Marine Diesel
Engines (NOx Technical Code). Following the entry into force, on 19
May 2005, of MARPOL Annex VI Regulations for the Prevention of Air Pollution
from Ships, each marine diesel engine to which regulation 13 of that Annex
applies, must comply with the provisions of this Code. MEPC 53 in July 2005 agreed
to the revision of MARPOL Annex VI and the NOx Technical Code. That
review was concluded at MEPC 58 in October 2008 and this version of the NOx
Technical Code, hereunder referred to as the Code, is an outcome of that
process.
As
general background information, the precursors to the formation of nitrogen
oxides during the combustion process are nitrogen and oxygen. Together these
compounds comprise 99% of the engine intake air. Oxygen will be consumed during
the combustion process, with the amount of excess oxygen available being a
function of the air/fuel ratio which the engine is operating under. The
nitrogen remains largely unreacted in the combustion process; however, a small
percentage will be oxidized to form various oxides of nitrogen. The nitrogen
oxides (NOx) which can be formed include nitric oxide (NO) and
nitrogen dioxide (NO2), while the amounts are primarily a function
of flame or combustion temperature and, if present, the amount of organic
nitrogen available from the fuel, NOx formation is also a function
of the time the nitrogen and the excess oxygen are exposed to the high
temperatures associated with the diesel engine's combustion process. In other
words, the higher the combustion temperature (e.g., high-peak pressure,
high-compression ratio, high rate of fuel delivery, etc.), the greater the
amount of NOx formation. A slow-speed diesel engine, in general,
tends to have more NOx formation than a high speed engine. NOx
has an adverse effect on the environment causing acidification, formation of
tropospheric ozone, nutrient enrichment and contributes to adverse health
effects globally.
The
purpose of this Code is to provide mandatory procedures for the testing, survey
and certification of marine diesel engines which will enable engine manufacturers,
shipowners and Administrations to ensure that all applicable marine diesel
engines comply with the relevant limiting emission values of NOx as
specified within regulation 13 of Annex VI. The difficulties of establishing
with precision, the actual weighted average NOx emission of marine
diesel engines in service on ships have been recognized in formulating a
simple, practical set of requirements in which the means to ensure compliance
with the allowable NOx emissions, are defined.
Administrations
are encouraged to assess the emissions performance of marine propulsion and
auxiliary diesel engines on a test bed where accurate tests can be carried out
under properly controlled conditions. Establishing compliance with regulation
13 of Annex VI at this initial stage is an essential feature of this Code.
Subsequent testing on board the ship may inevitably be limited in scope and
accuracy and its purpose shall be to infer or deduce the emission performance
and to confirm that engines are installed, operated and maintained in
accordance with the manufacturer's specifications and that any adjustments or
modifications do not detract from the emissions performance established by
initial testing and certification by the manufacturer.
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INTRODUCTION ................................................ |
Page 3 |
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FOREWORD
.................................................... |
3 |
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ABBREVIATIONS,
SUBSCRIPTS AND SYMBOLS ....................... |
7 |
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Chapter 1 -
GENERAL ......................................... |
10 |
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1.1 PURPOSE
................................................. |
10 |
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1.2 APPLICATION
............................................. |
10 |
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1.3 DEFINITIONS
............................................. |
10 |
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Chapter 2 -
SURVEYS AND CERTIFICATION ....................... |
13 |
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2.1 GENERAL
................................................. |
13 |
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2.2 PROCEDURES
FOR PRE-CERTIFICATION OF AN ENGINE ........... |
14 |
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2.3 PROCEDURES
FOR CERTIFICATION OF AN ENGINE ............... |
16 |
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2.4 TECHNICAL
FILE AND ONBOARD NOx VERIFICATION PROCEDURES |
17 |
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Chapter 3 -
NITROGEN OXIDES EMISSION STANDARDS .............. |
20 |
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3.1 MAXIMUM
ALLOWABLE NOx EMISSION LIMITS FOR MARINE DIESEL ENGINES
.............................................. |
20 |
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3.2 TEST CYCLES
AND WEIGHTING FACTORS TO BE APPLIED ......... |
20 |
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Chapter 4 -
APPROVAL FOR SERIALLY MANUFACTURED ENGINES: ENGINE FAMILY
AND ENGINE GROUP CONCEPTS ..................... |
23 |
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4.1 GENERAL
................................................. |
23 |
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4.2
DOCUMENTATION ........................................... |
23 |
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4.3 APPLICATION
OF THE ENGINE FAMILY CONCEPT ................ |
23 |
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4.4 APPLICATION
OF THE ENGINE GROUP CONCEPT ................. |
27 |
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Chapter 5 -
PROCEDURES FOR NOx EMISSION MEASUREMENTS ON A TEST BED
.................................................. |
30 |
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5.1 GENERAL
................................................. |
30 |
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5.2 TEST
CONDITIONS ......................................... |
30 |
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5.3 TEST FUEL
OILS .......................................... |
33 |
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5.4 MEASUREMENT
EQUIPMENT AND DATA TO BE MEASURED ........... |
33 |
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5.5
DETERMINATION OF EXHAUST GAS FLOW ....................... |
34 |
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5.6 PERMISSIBLE
DEVIATIONS OF INSTRUMENTS FOR ENGINE-RELATED PARAMETERS AND
OTHER ESSENTIAL PARAMETERS ................... |
35 |
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5.7 ANALYSERS
FOR DETERMINATION OF THE GASEOUS COMPONENTS ... |
35 |
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5.8 CALIBRATION
OF THE ANALYTICAL INSTRUMENTS ............... |
35 |
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5.9 TEST RUN
................................................ |
35 |
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5.10 TEST REPORT
............................................ |
37 |
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5.11 DATA EVALUATION
FOR GASEOUS EMISSIONS .................. |
38 |
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5.12 CALCULATION
OF THE GASEOUS EMISSIONS ................... |
38 |
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Chapter 6 -
PROCEDURES FOR DEMONSTRATING COMPLIANCE WITH NOx EMISSION LIMITS ON
BOARD................................ |
43 |
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6.1 GENERAL ................................................. |
43 |
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6.2 ENGINE
PARAMETER CHECK METHOD ........................... |
43 |
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6.3 SFMPLIFIED
MEASUREMENT METHOD ........................... |
46 |
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6.4 DIRECT
MEASUREMENT AND MONITORING METHOD ................ |
49 |
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Chapter 7 -
CERTIFICATION OF AN EXISTING ENGINE.............. |
55 |
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APPENDICES APPENDIX 1 -
Form of EIAPP Certificate ...................... |
56 |
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APPENDIX 2 -
Flowcharts for survey and certification of marine diesel
engines .................................... |
59 |
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APPENDIX 3 -
Specifications for analysers to be used in the
determination of gaseous components of marine diesel engine emissions
............................................ |
63 |
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APPENDIX 4 -
Calibration of the analytical and measurement instruments ................................................ |
68 |
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APPENDIX 5 -
Parent Engine test report and test data -Section 1 -
Parent Engine test report ...................... |
81 |
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- Section 2 -
Parent Engine test data to be included in the Technical
File |
89 |
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APPENDIX 6 -
Calculation of exhaust gas mass flow (carbon-balance
method) |
92 |
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APPENDIX 7 -
Checklist for an Engine Parameter Check method |
94 |
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APPENDIX 8 -
Implementation of the Direct Measurement and Monitoring
method |
97 |
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Abbreviations, Subscripts and Symbols
Tables
1, 2, 3 and 4 below summarize the abbreviations, subscripts and symbols used
throughout the Code, including specifications for the analytical instruments in
appendix 3, calibration requirements for the analytic instruments contained in
appendix 4, the formulae for calculation of gas mass flow as contained in
chapter 5 and appendix 6 of this Code and the symbols used in respect of data
for onboard verification surveys in chapter 6.
.1 Table 1: symbols used to
represent the chemical components of diesel engine gas emissions and
calibration and span gases addressed throughout this Code;
.2 Table 2: abbreviations
for the analysers used in the measurement of gas emissions from diesel engines
as specified in appendix 3 of this Code;
.3 Table 3: symbols and
subscripts of terms and variables used in chapter 5, chapter 6, appendix 4 and
appendix 6 of this Code; and
.4 Table 4: symbols for fuel
composition used in chapter 5 and chapter 6 and appendix 6 of this Code.
Table
1.
Symbols and abbreviations for the chemical components
|
Symbol |
Definition |
|
CH4 |
Methane |
|
C3H8 |
Propane |
|
CO |
Carbon monoxide |
|
CO2 |
Carbon dioxide |
|
HC |
Hydrocarbons |
|
H2O |
Water |
|
NO |
Nitric oxide |
|
NO2 |
Nitrogen dioxide |
|
NOx |
Nitrogen oxides |
|
O2 |
Oxygen |
Table
2.
Abbreviations for Analysers for measurement of diesel engine gaseous emissions
(refer to appendix 3 of this Code)
|
CLD |
Chemiluminescent
detector |
|
ECS |
Electrochemical
sensor |
|
HCLD |
Heated
chemiluminescent detector |
|
HFID |
Heated flame
ionization detector |
|
NDIR |
Non-dispersive
infrared analyser |
|
PMD |
Paramagnetic
detector |
|
ZRDO |
Zirconium
dioxide sensor |
Table
3.
Symbols and subscripts for terms and variables
(refer to chapter 5, chapter 6, appendix 4 and appendix 6 of this Code)
|
Symbol |
Term |
Unit |
|
A/Fst |
Stoichiometric
air to fuel ratio |
1 |
|
cx |
Concentration in
the exhaust (with suffix of the component
nominating, d=dry or w=wet) |
ppm/% (V/V) |
|
ECO2 |
CO2
quench of NOx analyser |
% |
|
EH2O |
Water quench of
NOx analyser |
% |
|
ENOx |
Efficiency of NOx
converter |
% |
|
EO2 |
Oxygen analyser
correction factor |
1 |
|
λ |
Excess air
factor: kg dry air/(kg fuel A/Fst) |
1 |
|
fa |
Test condition
parameter |
1 |
|
fc |
Carbon factor |
1 |
|
ffd |
Fuel specific
factor for exhaust flow calculation on dry basis |
1 |
|
ffw |
Fuel specific
factor for exhaust flow calculation on wet basis |
1 |
|
Ha |
Absolute humidity
of the intake air (g water / kg dry air) |
g/kg |
|
HSC |
Humidity of the
charge air |
g/kg |
|
i |
Subscript
denoting an individual mode |
1 |
|
khd |
Humidity
correction factor for NOx for diesel engines |
1 |
|
kwa |
Dry to wet
correction factor for the intake air |
1 |
|
kwr |
Dry to wet
correction factor for the raw exhaust gas |
1 |
|
nd |
Engine speed |
min-1 |
|
nturb |
Turbocharger
speed |
min-1 |
|
%O2I |
HC analyser
percentage oxygen interference |
% |
|
pa |
Saturation
vapour pressure of the engine intake air determined using
a temperature value for the intake air measured at the
same physical location as the measurements for
pb and Ra |
kPa |
|
pb |
Total barometric
pressure |
kPa |
|
pC |
Charge air
pressure |
kPa |
|
pr |
Water vapour
pressure after cooling bath of the analysis system |
kPa |
|
ps |
Dry atmospheric
pressure calculated by the following formula: ps
= pb - Rapa/100 |
kPa |
|
pSC |
Saturation
vapour pressure of the charge air |
kPa |
|
P |
Uncorrected
brake power |
kW |
|
Paux |
Declared total
power absorbed by auxiliaries fitted for the test and not
required by ISO 14396 |
kW |
|
Pm |
Maximum measured
or declared power at the test engine speed under test
conditions |
kW |
|
qmad |
Intake air mass
flow rate on dry basis |
kg/h |
|
Symbol |
Term |
Unit |
|
qmaw |
Intake air mass
flow rate on wet basis |
kg/h |
|
qmew |
Exhaust gas mass
flow rate on wet basis |
kg/h |
|
qmf |
Fuel mass flow
rate |
kg/h |
|
qmgas |
Emission mass
flow rate of individual gas |
g/h |
|
Ra |
Relative
humidity of the intake air |
% |
|
h |
Hydrocarbon
response factor |
1 |
|
P |
Density |
kg/m3 |
|
s |
Fuel rack
position |
|
|
Ta |
Intake air
temperature determined at the engine intake |
K |
|
Tcaclin |
Charge air
cooler, coolant inlet temperature |
C |
|
Tcaclout |
Charge air
cooler, coolant outlet temperature |
C |
|
TExh |
Exhaust gas
temperature |
C |
|
TFuel |
Fuel oil
temperature |
C |
|
TSea |
Seawater
temperature |
C |
|
TSC |
Charge air
temperature |
K |
|
TSCRef |
Charge air
reference temperature |
K |
|
U |
Ratio of exhaust
component and exhaust gas densities |
1 |
|
WF |
Weighting factor |
1 |
Table
4.
Symbols
for fuel composition
|
Symbol |
Definition |
|
WALF |
H content of
fuel, % m/m |
|
wBET |
C content of
fuel, % m/m |
|
wGAM |
S content of
fuel, % m/m |
|
wDEL |
N content of
fuel, % m/m |
|
wEPS |
O content of
fuel, % m/m |
|
α |
molar ratio
(H/C) |
1.1.1
The purpose of this Technical Code on Control of Emission of Nitrogen Oxides
from Marine Diesel Engines, hereunder referred to as the Code, is to specify
the requirements for the testing, survey and certification of marine diesel
engines to ensure they comply with the nitrogen oxides (NOx)
emission limits of regulation 13 of Annex VI. All references to regulations
within this Code refer to Annex VI.
1.2.1
This Code applies to all marine diesel engines with a power output of more than
130 kW which are installed, or are designed and intended for installation, on
board any ship subject to Annex VI and to which regulation 13 applies.
Regarding the requirements for survey and certification under regulation 5,
this Code addresses only those requirements applicable to an engine's
compliance with the applicable NOx emission limit.
1.2.2
For the purpose of the application of this Code, Administrations are entitled
to delegate all functions required of an Administration by this Code to an
organization authorized to act on behalf of the Administration1. In
every case, the Administration assumes full responsibility for the survey and
certificate.
______________
1 Refer to the Guidelines for
the Authorization of Organizations Acting on Behalf of Administrations adopted
by the Organization by resolution A.739(18) and to the Specifications on the
Survey and Certification Functions of Recognized Organizations Acting on Behalf
of the Administration adopted by the Organization by resolution A.789(19).
1.2.3
For the purpose of this Code, an engine shall be considered to be operated in
compliance with the applicable NOx limit of regulation 13 if it can
be demonstrated that the weighted NOx emissions from the engine are
within those limits at the initial certification, annual, intermediate and
renewal surveys and such other surveys as are required.
1.3.1
Nitrogen Oxide (NOx) emissions means the total emission of nitrogen
oxides, calculated as the total weighted emission of NO2 and
determined using the relevant test cycles and measurement methods as specified
in this Code.
1.3.2
Substantial modification of a marine diesel engine means:
.1 For engines installed on
ships constructed on or after 1 January 2000, substantial modification means
any modification to an engine that could potentially cause the engine to exceed
the applicable emission limit set out in regulation 13. Routine replacement of
engine components by parts specified in the Technical File that do not alter
emission characteristics shall not be considered a "substantial
modification" regardless of whether one part or many parts are replaced.
.2 For engines installed on
ships constructed before 1 January 2000, substantial modification means any
modification made to an engine which increases its existing emission
characteristics established by the Simplified Measurement method as described
in 6.3 in excess of the allowances set out in 6.3.11. These changes include,
but are not limited to, changes in its operations or in its technical
parameters (e.g., changing camshafts, fuel injection systems, air systems,
combustion chamber configuration, or timing calibration of the engine). The
installation of a certified Approved Method pursuant to regulation 13.7.1.1 or
certification pursuant to regulation 13.7.1.2 is not considered to be a
substantial modification for the purpose of the application of regulation 13.2
of the Annex.
1.3.3
Components are those interchangeable parts which influence the NOx
emissions performance, identified by their design/parts number.
1.3.4
Setting means adjustment of an adjustable feature influencing the NOx
emissions performance of an engine.
1.3.5
Operating values are engine data, like cylinder peak pressure, exhaust gas
temperature, etc., from the engine log which are related to the NOx
emission performance. These data are load-dependent.
1.3.6
The EIAPP Certificate is the Engine International Air Pollution Prevention
Certificate which relates to NOx emissions.
1.3.7
The IAPP Certificate is the International Air Pollution Prevention Certificate.
1.3.8
Administration has the same meaning as article 2, subparagraph (5) of MARPOL
73.
1.3.9
Onboard NOx verification procedures mean a procedure, which may
include an equipment requirement, to be used on board at initial certification
survey or at the renewal, annual or intermediate surveys, as required, to
verify compliance with any of the requirements of this Code, as specified by
the applicant for engine certification and approved by the Administration.
1.3.10
Marine diesel engine means any reciprocating internal combustion engine
operating on liquid or dual fuel, to which regulation 13 applies, including
booster/compound systems if applied.
Where
an engine is intended to be operated normally in the gas mode, i.e. with the
main fuel gas and only a small amount of liquid pilot fuel, the requirements of
regulation 13 have to be met only for this operation mode. Operation on pure
liquid fuel resulting from restricted gas supply in cases of failures shall be
exempted for the voyage to the next appropriate port for the repair of the
failure.
1.3.11
Rated power means the maximum continuous rated power output