IMDG Code. Part 7 (2018)

THE INTERNATIONAL MARITIME DANGEROUS GOODS (IMDG) CODE

AMENDMENT 38-16

 (adopted on 13 May 2016 by MSC.406(96))

enter into force on 1 January 2018

 

PART 7

PROVISIONS CONCERNING TRANSPORT OPERATIONS

 

Chapter 7.1. General stowage provisions

7.1.1 Introduction

This chapter contains the general provisions for the stowage of dangerous goods in all types of ships. Specific provisions applicable to, container ships, ro-ro ships, general cargo ships and barge carrying ships, are stipulated in chapters 7.4 to 7.7.

7.1.2 Definitions

Note 1: The term “magazine” is no longer used in the context of the IMDG Code. A magazine that is not a fixed part of the ship shall meet the provisions for a closed cargo transport unit for class 1 (see 7.1.2). A magazine that is a fixed part of the ship such as compartment, below deck area or hold shall meet the provisions of 7.6.2.4.

Note 2: Cargo holds cannot be interpreted as closed cargo transport units.

Clear of living quarters means that packages or cargo transport units shall be stowed a minimum distance of 3 m from accommodation, air intakes, machinery spaces and other enclosed work areas.

Closed cargo transport unit for class 1 means a unit which fully encloses the contents by permanent structures, can be secured to the ship’s structure and is, except for division 1.4, structurally serviceable as defined in this section. Cargo transport units with fabric sides or tops are not closed cargo transport units. The floor of any closed cargo transport unit shall either be constructed of wood, close-boarded, or so arranged that goods are stowed on sparred gratings, wooden pallets or dunnage.

Combustible material means material which may or may not be dangerous goods but which is easily ignited and supports combustion. Examples of combustible materials include wood, paper, straw, vegetable fibres, products made from such materials, coal, lubricants, and oils. This definition does not apply to packaging material or dunnage.

Potential sources of ignition means, but is not limited to, open fires, machinery exhausts, galley uptakes, electrical outlets and electrical equipment including those on refrigerated or heated cargo transport units unless they are of certified safe type.*

_____________________

*    For cargo spaces, refer to SOLAS II-2/19.3.2 and for refrigerated or heated cargo transport units refer to Recommendations published by the International Electrotechnical Commission, in particular IEC 60079.

 

Protected from sources of heat means that packages and cargo transport units shall be stowed at least 2.4 m from heated ship structures, where the surface temperature is liable to exceed 55°C. Examples of heated structures are steam pipes, heating coils, top or side walls of heated fuel and cargo tanks, and bulkheads of machinery spaces. In addition, packages not loaded inside a cargo transport unit and stowed on deck shall be shaded from direct sunlight. The surface of a cargo transport unit can heat rapidly when in direct sunlight in nearly windless conditions and the cargo may also become heated. Depending on the nature of the goods in the cargo transport unit and the planned voyage precautions shall be taken to ensure that exposure to direct sunlight is reduced.

Stowage means the proper placement of dangerous goods on board a ship in order to ensure safety and environmental protection during transport.

Stowage on deck means stowage on the weather deck. For open ro-ro cargo spaces see 7.5.2.6.

Stowage under deck means any stowage that is not on the weather deck. For hatchless containerships see 7.4.2.1.

Structurally serviceable for class 1 means the cargo transport unit shall not have major defects in its structural components, e.g. top and bottom rails, top and bottom end rails, door sill and header, floor cross-members, corner posts, and corner fittings in a freight container. Major defects are: dents or bends in the structural members greater than 19 mm in depth, regardless of length; cracks or breaks in structural members; more than one splice (e.g. a lapped splice) in top or bottom end rails or door headers; more than two splices in any one top or bottom side rail or any splice in a door sill or corner post; door hinges and hardware that are seized, twisted, broken, missing or otherwise inoperative; gaskets and seals that do not seal; or, for freight containers, any distortion of the overall configuration great enough to prevent proper alignment of handling equipment, mounting and securing on chassis or vehicle, or insertion into ship’s cells. In addition, deterioration in any component of the cargo transport unit, regardless of the material of construction, such as rusted-out metal in sidewalls or disintegrated fibreglass, is unacceptable. Normal wear, however, including oxidation (rust), slight dents and scratches and other damage that does not affect serviceability or the weathertight integrity of the units, is acceptable.

7.1.3 Stowage categories

7.1.3.1 Stowage categories for class 1

Dangerous goods of class 1 other than division 1.4, compatibility group S, packed in limited quantities shall be stowed as indicated in column 16a of the Dangerous Goods List in accordance with one of the categories specified below.

Stowage category 01

Cargo ships

(up to 12 passengers)

On deck in closed cargo transport unit or under deck

 

Passenger ships

On deck in closed cargo transport unit or under deck

Stowage category 02

Cargo ships

(up to 12 passengers)

On deck in closed cargo transport unit or under deck

 

Passenger ships

On deck in closed cargo transport unit or under deck in closed cargo transport unit in accordance with 7.1.4.4.5

Stowage category 03

Cargo ships

(up to 12 passengers)

On deck in closed cargo transport unit or under deck

 

Passenger ships

Prohibited except if in accordance with 7.1.4.4.5

 Stowage category 04

Cargo ships

(up to 12 passengers)

On deck in closed cargo transport unit or under deck in closed cargo transport unit

 

Passenger ships

Prohibited except if in accordance with 7.1.4.4.5

Stowage category 05

Cargo ships

(up to 12 passengers)

On deck only in closed cargo transport unit

 

Passenger ships

Prohibited except if in accordance with 7.1.4.4.5

 

7.1.3.2 Stowage categories for classes 2 to 9

Dangerous goods of classes 2 to 9 and division 1.4, compatibility group S, packed in limited quantities shall be stowed as indicated in column 16a of the Dangerous Goods List in accordance with one of the categories specified below:

Stowage category A

 

Cargo ships or passenger ships carrying a number of passengers limited to not more than 25 or to 1 passenger per 3 m of overall length, whichever is the greater number

Other passenger ships in which the limiting number of passengers transported is exceeded

} ON DECK OR UNDER DECK

}

 

} ON DECK OR UNDER DECK

Stowage category B

 

Cargo ships or passenger ships carrying a number of passengers limited to not more than 25 or to 1 passenger per 3 m of overall length, whichever is the greater number

Other passenger ships in which the limiting number of passengers transported is exceeded

} ON DECK OR UNDER DECK

}

 

}ON DECK ONLY

Stowage category C

 

Cargo ships or passenger ships carrying a number of passengers limited to not more than 25 or to 1 passenger per 3 m of overall length, whichever is the greater number

Other passenger ships in which the limiting number of passengers transported is exceeded

} ON DECK ONLY

}

 

} ON DECK ONLY

Stowage category D

 

Cargo ships or passenger ships carrying a number of passengers limited to not more than 25 or to 1 passenger per 3 m of overall length, whichever is the greater number

Other passenger ships in which the limiting number of passengers  transported is exceeded

} ON DECK ONLY

}

 

} PROHIBITED

Stowage category E

 

Cargo ships or passenger ships carrying a number of passengers limited to not more than 25 or to 1 passenger per 3 m of overall length, whichever is the greater number

Other passenger ships in which the limiting number of passengers transported is exceeded

} ON DECK OR UNDER DECK

}

 

} PROHIBITED

 

7.1.4 Special stowage provisions

7.1.4.1 Stowage of empty uncleaned packagings, including IBCs and large packagings

Notwithstanding the stowage provisions given in the Dangerous Goods List, empty uncleaned packagings, including IBCs and large packagings, which shall be stowed on deck only when full may be stowed on deck or under deck in a mechanically ventilated cargo space. However, empty uncleaned pressure receptacles which carry a label of class 2.3 shall be stowed on deck only (see also 4.1.1.11) and waste aerosols shall only be stowed according to column 16a of the Dangerous Goods List.

7.1.4.2 Stowage of marine pollutants

Where stowage is permitted on deck or under deck, under deck stowage is preferred. Where stowage on deck only is required, preference shall be given to stowage on well-protected decks or to stowage inboard in sheltered areas of exposed decks.

7.1.4.3 Stowage of limited quantities and excepted quantities

For the stowage of limited quantities and excepted quantities see sections 3.4 and 3.5.

7.1.4.4 Stowage of goods of class 1

7.1.4.4.1 In cargo ships of 500 gross tons or over and passenger ships constructed before 1 September 1984 and in cargo ships of less than 500 gross tons constructed before 1 February 1992, goods of class 1 with the exception of division 1.4, compatibility group S, shall be stowed on deck only, unless otherwise approved by the Administration.

7.1.4.4.2 Goods of class 1 with the exception of division 1.4 shall be stowed not less than a horizontal distance of 12 m from living quarters, life-saving appliances and areas with public access.

7.1.4.4.3 Goods of class 1 with the exception of division 1.4 shall not be positioned closer to the ship’s side than a distance equal to one eighth of the beam or 2.4 m, whichever is the lesser.

7.1.4.4.4 Goods of class 1 shall not be stowed within a horizontal distance of 6 m from potential sources of ignition.

7.1.4.4.5 Stowage on passenger ships

7.1.4.4.5.1 Goods in division 1.4, compatibility group S, may be transported in any amount on passenger ships. No other goods of class 1 may be transported on passenger ships except:

.1       goods in compatibility groups C, D and E and articles in compatibility group G, if the total net explosive mass does not exceed 10 kg per ship and if they are transported in closed cargo transport units on deck or under deck;

.2       articles in compatibility group B, if the total net explosive mass does not exceed 10 kg per ship and if they are transported on deck only in closed cargo transport units.

7.1.4.4.6 Alternative arrangements to those prescribed in chapter 7.1 for class 1 may be approved by the Administration.

7.1.4.5 Stowage of goods of class 7

7.1.4.5.1 The total activity in a single cargo space of a sea going vessel for transport of LSA material or SCO in Type IP 1, Type IP 2, Type IP 3 packaging or unpackaged shall not exceed the limits shown in the table hereunder.

Conveyance activity limits for LSA material and SCO in industrial packages or unpackaged

Nature of material

Activity limit for a seagoing vessel

LSA I

No limit

LSA II and LSA III non-combustible solids

No limit

LSA II and LSA III combustible solids, and all liquids and gases

100A2

SCO

100A2

 

7.1.4.5.2 Provided that its average surface heat flux does not exceed 15 W/m2 and that the immediately surrounding cargo is not in sacks or bags, a package or overpack may be transported or stored among packaged general cargo without any special stowage provisions except as may be specifically required by the competent authority in an applicable certificate of approval.

7.1.4.5.3 Loading of freight containers and accumulation of packages, overpacks and freight containers shall be controlled as follows:

.1       Except under the condition of exclusive use, the total number of packages, overpacks and freight containers aboard a single conveyance shall be so limited that the total sum of the transport indexes aboard the conveyance does not exceed the values shown in the table hereunder. For consignments of LSA I material there shall be no limit on the sum of the transport indexes.

TI limits for freight containers and conveyances not under exclusive use

Type of freight container or conveyance

Limit on total sum of transport indexes in a freight container or aboard a conveyance

Freight container

Small freight container

Large freight container

50

50

Vehicle

50

Inland water-way vessel (barge)

50

Seagoing vessela

1 Hold, compartment or defined deck area Packages, overpacks, small freight containers

Large freight containers (closed containers)

50

200

2 Total vessel

Packages, overpacks, small freight containers

Large freight containers (closed containers)

200

No limit

a    Packages or overpacks transported in or on a vehicle which are in accordance with the provisions of 7.1.4.5.5 may be transported by vessels provided that they are not removed from the vehicle at any time while on board the ship.

 

.2       Where a consignment is transported under exclusive use, there shall be no limit on the sum of the transport indexes aboard a single conveyance.

.3       The radiation level under routine conditions of transport shall not exceed 2 mSv/h at any point on, and 0.1 mSv/h at 2 m from, the external surface of the conveyance, except for consignments transported under exclusive use by road or rail, for which the radiation limits around the vehicle are specified in 7.1.4.5.5.2 and 7.1.4.5.5.3.

.4       The total sum of the criticality safety indexes in a freight container and aboard a conveyance shall not exceed the values shown in the table hereunder.

CSI limits for freight containers and conveyances containing fissile material

Type of freight container or conveyance

Limit on total sum of criticality safety indexes in a freight container or aboard a conveyance

Not under exclusive use

Under exclusive use

Freight container

Small freight container

Large freight container

50

50

n.a.

100

Vehicle

50

100

Inland water-way vessel (barge)

50

100

Seagoing vessela

1 Hold, compartment or defined deck area

Packages, overpacks, small freight containers

Large freight containers (closed containers)

50

50

100

100

2 Total vessel

Packages, overpacks, small freight containers

Large freight containers (closed containers)

200b

No limitb

200c

No limitc

 

a     Packages or overpacks transported in or on a vehicle which are in accordance with the provisions of 7.1.4.5.5 may be transported by ships provided that they are not removed from the vehicle at any time while on board the ship. In that case, the entries under the heading “under exclusive use” apply.

b     The consignment shall be so handled and stowed that the total sum of CSIs in any group does not exceed 50, and that each group is handled and stowed so as to maintain a spacing of at least 6 m from other groups.

c     The consignment shall be so handled and stowed that the total sum of CSIs in any group does not exceed 100, and that each group is handled and stowed so as to maintain a spacing of at least 6 m from other groups. The intervening space between groups may be occupied by other cargo.

7.1.4.5.4 Any package or overpack having either a transport index greater than 10, or any consignment having a criticality safety index greater than 50, shall be transported only under exclusive use.

7.1.4.5.5 For consignments under exclusive use, the radiation level shall not exceed:

.1       10 mSv/h at any point on the external surface of any package or overpack, and may only exceed 2 mSv/h provided that:

.1       the vehicle is equipped with an enclosure which, during routine conditions of transport, prevents the access of unauthorized persons to the interior of the enclosure, and

.2       provisions are made to secure the package or overpack so that its position within the vehicle enclosure remains fixed during routine conditions of transport, and

.3       there is no loading or unloading during the shipment;

.2       2 mSv/h at any point on the outer surfaces of the vehicle, including the upper and lower surfaces, or, in the case of an open vehicle, at any point on the vertical planes projected from the outer edges of the vehicle, on the upper surface of the load, and on the lower external surface of the vehicle; and

.3       0.1 mSv/h at any point 2 m from the vertical planes represented by the outer lateral surfaces of the vehicle, or, if the load is transported in an open vehicle, at any point 2 m from the vertical planes projected from the outer edges of the vehicle.

7.1.4.5.6 In the case of road vehicles, no persons other than the driver and assistants shall be permitted in vehicles carrying packages, overpacks or freight containers bearing category II-YELLOW or III-YELLOW labels.

7.1.4.5.7 Packages or overpacks having a surface radiation level greater than 2 mSv/h, unless being transported in or on a vehicle under exclusive use in accordance with the table under 7.1.4.5.3, footnote (a), shall not be transported by ship except under special arrangement.

7.1.4.5.8 The transport of consignments by means of a special use ship which, by virtue of its design or by reason of its being chartered, is dedicated to the purpose of carrying radioactive material shall be excepted from the provisions specified in 7.1.4.5.3 provided that the following conditions are met:

.1       a radiation protection programme for the shipment shall be approved by the Administration and, when requested, by the competent authority at each port of call;

.2       stowage arrangements shall be predetermined for the whole voyage, including any consignments to be loaded at ports of call en route; and

.3       the loading, transport and unloading of the consignments shall be supervised by persons qualified in the transport of radioactive material.

7.1.4.5.9 Any conveyance and equipment used regularly for the transport of radioactive material shall be periodically checked to determine the level of contamination. The frequency of such checks shall be related to the likelihood of contamination and the extent to which radioactive material is transported.

7.1.4.5.10 Except as provided in 7.1.4.5.11, any conveyance, or equipment or part thereof, which has become contaminated above the limits specified in 4.1.9.1.2 in the course of the transport of radioactive material, or which shows a radiation level in excess of 5 µSv/h at the surface, shall be decontaminated as soon as possible by a qualified person and shall not be re-used unless the following conditions are fulfilled:

.1       the non-fixed contamination shall not exceed the limits specified in 4.1.9.1.2;

.2       the radiation level resulting from the fixed contamination shall not exceed 5 μSv/h at the surface.

7.1.4.5.11 A freight container, tank, IBC or conveyance dedicated to the transport of unpackaged radioactive material under exclusive use shall be excepted from the provisions of 4.1.9.1.4 and 7.1.4.5.10 solely with regard to its internal surfaces and only for as long as it remains under that specific exclusive use.

7.1.4.5.12 Where a consignment is undeliverable, the consignment shall be placed in a safe location and the appropriate competent authority shall be informed as soon as possible and a request made for instructions on further action.

7.1.4.5.13 Radioactive material shall be segregated sufficiently from crew and passengers. The following values for dose shall be used for the purpose of calculating segregation distances or radiation levels:

.1       for crew in regularly occupied working areas, a dose of 5 mSv in a year;

.2       for passengers, in areas where the passengers have regular access, a dose of 1 mSv in a year, taking account of the exposures expected to be delivered by all other relevant sources and practices under control.

7.1.4.5.14 Category II-YELLOW or III-YELLOW packages or overpacks shall not be transported in spaces occupied by passengers, except those exclusively reserved for couriers specially authorized to accompany such packages or overpacks.

7.1.4.5.15 Any group of packages, overpacks and freight containers containing fissile material stored in transit in any one storage area shall be so limited that the total sum of the criticality safety indexes in the group does not exceed 50. Each group shall be stored so as to maintain a spacing of at least 6 m from other such groups.

7.1.4.5.16 Where the total sum of the criticality safety indexes on board a conveyance or in a freight container exceeds 50, as permitted in the table under 7.1.4.5.3.4, storage shall be such as to maintain a spacing of at least 6 m from other groups of packages, overpacks or freight containers containing fissile material or other conveyances carrying radioactive material.

7.1.4.5.17 Any departure from the provisions in 7.1.4.5.15 and 7.1.4.5.16 shall be approved by the Administration and, when requested, by the competent authority at each port of call.

7.1.4.5.18 The segregation requirements specified in 7.1.4.5.13 may be established in one of the following two ways:

     by following the segregation table for persons (table 7.1.4.5.18) in respect of living quarters or spaces regularly occupied by persons.

     by demonstration that, for the following indicated exposure times, the direct measurement of the radiation level in regularly occupied spaces and living quarters is less than:

for the crew:

0.0070 mSv/h up to 700 h in a year, or

0.0018 mSv/h up to 2750 h in a year; and

for the passengers:

0.0018 mSv/h up to 550 h in a year,

taking into account any relocation of cargo during the voyage. In all cases, the measurements of radiation level must be made and documented by a suitably qualified person.

7.1.4.6 Stowage of dangerous goods under temperature control

7.1.4.6.1 When stowage arrangements are made, it shall be borne in mind that it may become necessary to take the appropriate emergency action, such as jettisoning or flooding of the container with water, and the temperature needs to be monitored in accordance to 7.3.7. If, during transport, the control temperature is exceeded, an alerting procedure shall be initiated involving either repair of the refrigeration machinery or an increase in the cooling capacity (such as by adding liquid or solid refrigerants). If an adequate cooling capacity is not restored, emergency procedures shall be started.

Table 7.1.4.5.18 – CLASS 7 – Radioactive material

Segregation table for persons

Sum of transport indices (TI)

Segregation distance of radioactive material from passengers and crew

General cargo ship1

Ferry, etc.2

Offshore support vessel3

Break bulk (m)

Containers (TEUs)4

Up to 10

6

1

Stow at bow or stern furthest from living quarters and regularly occupied work areas

Stow at stern or at platform midpoint

More than 10 but not more than 20

8

1

as above

as above

More than 20 but not more than 50

13

2

as above

not applicable

More than 50 but not more than 100

18

3

as above

not applicable

More than 100 but not more than 200

26

4

as above

not applicable

More than 200 but not more than 400

36

6

as above

not applicable

 

1    General cargo, break bulk or ro-ro containership of 150 m minimum length.

2    Ferry or cross channel, coastal and inter-island ship of 100 m minimum length.

3    Offshore support vessel of 50 m minimum length (in this case the practical maximum sum of TIs carried is 20).

4    TEU means “20 ft Equivalent Unit” (this is equivalent to a standard freight container of 6 m nominal length).

 

7.1.5 Stowage codes

The stowage codes given in column 16a of the Dangerous Goods List are as specified below:

Stowage code

Description

SW1

Protected from sources of heat.

SW2

Clear of living quarters.

SW3

Shall be transported under temperature control.

SW4

Surface ventilation is required to assist in removing any residual solvent vapour.

SW5

If under deck, stow in a mechanically ventilated space.

SW6

When stowed under deck, mechanical ventilation shall be in accordance with SOLAS regulation II-2/19 (II-2/54) for flammable liquids with flashpoint below 23°C c.c.

SW7

As approved by the competent authorities of the countries involved in the shipment.

SW8

Ventilation may be required. The possible need to open hatches in case of fire to provide maximum ventilation and to apply water in an emergency, and the consequent risk to the stability of the ship through flooding of the cargo spaces, shall be considered before loading.

SW9

Provide a good through ventilation for bagged cargo. Double strip stowage is recommended. The illustration in 7.6.2.7.2.3 shows how this can be achieved. During the voyage regular temperature readings shall be taken at varying depths in the hold and recorded. If the temperature of the cargo exceeds the ambient temperature and continues to increase, ventilation shall be closed down.

SW10

Unless carried in closed cargo transport units, bales shall be properly covered by tarpaulins or the like. Cargo spaces shall be clean, dry and free from oil or grease. Ventilator cowls leading into the cargo space shall have sparking-preventing screens. All other openings, entrances and hatches leading to the cargo space shall be securely closed. During temporary interruption of loading, when the hatch remains uncovered, a fire-watch shall be kept. During loading or discharge, smoking in the vicinity shall be prohibited and fire-fighting appliances kept ready for immediate operation.

SW11

Cargo transport units shall be shaded from direct sunlight. Packages in cargo transport units shall be stowed so as to allow for adequate air circulation throughout the cargo.

SW12

Taking account of any supplementary requirements specified in the transport documents.

SW13

Taking account of any supplementary requirements specified in the competent authority approval certificate(s).

SW14

Category A only if the special stowage provisions of 7.4.1.4 and 7.6.2.8.4 are complied with.

SW15

For metal drums, stowage category B.

SW16

For unit loads in open cargo transport units, stowage category B.

SW17

Category E, for closed cargo transport unit and pallet boxes only. Ventilation may be required. The possible need to open hatches in case of fire to provide maximum ventilation and to apply water in an emergency, and the consequent risk to the stability of the ship through flooding of the cargo space, shall be considered before loading.

SW18

Category A, when transported in accordance with P650.

SW19

For batteries transported in accordance with special provisions 376 or 377, category C, unless transported on a short international voyage.

SW20

For uranyl nitrate hexahydrate solution stowage, category D applies.

SW21

For uranium metal pyrophoric and thorium metal pyrophoric stowage, category D applies.

SW22

For AEROSOLS with a maximum capacity of 1 L: category A.

For AEROSOLS with a capacity above 1 L: category B.

For WASTE AEROSOLS: category C, clear of living quarters.

SW23

When transported in BK3 bulk container, see 7.6.2.12 and 7.7.3.9.

SW24

For special stowage provisions, see 7.4.1.3 and 7.6.2.7.2.

SW25

For special stowage provisions, see 7.6.2.7.3.

SW26

For special stowage provisions, see 7.4.1.4 and 7.6.2.11.1.1.

SW27

For special stowage provisions, see 7.6.2.7.2.1.

SW28

As approved by the competent authority of the country of origin.

SW29

For engines or machinery containing fuels with flashpoint equal or greater than 23°C, stowage Category A.

 

7.1.6 Handling codes

The handling codes given in column 16a of the Dangerous Goods List are as specified below:

Handling code

Description

H1

Keep as dry as reasonably practicable.

H2

Keep as cool as reasonably practicable.

H3

During transport, it should be stowed (or kept) in a cool ventilated place.

H4

If cleaning of cargo spaces has to be carried out at sea, the safety procedures followed and standard of equipment used shall be at least as effective as those employed as industry best practice in a port. Until such cleaning is undertaken, the cargo spaces in which the asbestos has been carried shall be closed and access to those spaces shall be prohibited.

 

Chapter 7.2. General segregation provisions

7.2.1 Introduction

This chapter contains the general provisions for the segregation of goods which are mutually incompatible.

Additional segregation provisions are given in:

7.3     Consigning operations concerning the packing and use of cargo transport units (CTUs) and related provisions;

7.4     Stowage and segregation on containerships;

7.5     Stowage and segregation on roll-on/roll-off ships;

7.6     Stowage and segregation on general cargo ships; and

7.7     Shipborne barges on barge-carrying ships.

7.2.2 Definitions

7.2.2.1 Segregation

Segregation is the process of separating two or more substances or articles which are considered mutually incompatible when their packing or stowage together may result in undue hazards in case of leakage or spillage, or any other accident.

However, as the extent of the hazard arising may vary, the segregation arrangements required may also vary as appropriate. Segregation is obtained by maintaining certain distances between incompatible dangerous goods or by requiring the presence of one or more steel bulkheads or decks between them, or a combination thereof. Intervening spaces between such dangerous goods may be filled with other cargo compatible with the dangerous substances or articles in question.

7.2.2.2 Segregation terms

The following segregation terms that are used throughout this Code are defined in other chapters of this part as they apply to packing cargo transport units and segregation on board different ship types:

.1       “away from”;

.2       “separated from”;

.3       “separated by a complete compartment or hold from”;

.4       “separated longitudinally by an intervening complete compartment or hold from”.

Segregation terms such as “away from class …” that are used in the Dangerous Goods List, “class …” is deemed to include:

.1       all substances within “class …”; and

.2       all substances for which a subsidiary risk label of “class …” is required.

7.2.3 Segregation provisions

7.2.3.1 To determine the segregation requirements between two or more dangerous goods, the segregation provisions, including the segregation table (7.2.4) and column 16b of the Dangerous Goods List shall be consulted, see also the annex to this chapter. In case of conflicting provisions, the provisions of column 16b of the Dangerous Goods List, always take precedence.

7.2.3.2 Whenever a segregation term applies (see 7.2.2.2), the goods are:

.1       not permitted to be packed in the same outer packaging; and

.2       not permitted to be transported in the same cargo transport unit except as provided in 7.2.6 and 7.3.4.

For “limited quantities” and “excepted quantities” see chapters 3.4 and 3.5.

7.2.3.3 Where the provisions of this Code indicate a single secondary hazard (one subsidiary risk label), the segregation provisions applicable to that hazard shall take precedence where they are more stringent than those of the primary hazard. The segregation provisions corresponding to a subsidiary risk of class 1 are those for class 1 division 1.3.

7.2.3.4 The segregation provisions for substances, materials or articles having more than two hazards (two or more subsidiary risk labels) are given in column 16b of the Dangerous Goods List.

For example:

In the Dangerous Goods List entry for BROMINE CHLORIDE, class 2.3, UN 2901, subsidiary risks 5.1 and 8, the following particular segregation is specified:

“segregation as for class 5.1, but “separated from” class 7”.

7.2.4 Segregation table

The general provisions for segregation between the various classes of dangerous goods are shown in the “segregation table” given below.

Since the properties of substances, materials or articles within each class may vary greatly, the Dangerous Goods List shall always be consulted for particular provisions for segregation as, in the case of conflicting provisions, these take precedence over the general provisions.

Segregation shall also take account of a single subsidiary risk label.

CLASS

1.1

1.2

1.5

1.3

1.6

1.4

2.1

2.2

2.3

3

4.1

4.2

4.3

5.1

5.2

6.1

6.2

7

8

9

Explosives

1.1, 1.2, 1.5

*

*

*

4

2

2

4

4

4

4

4

4

2

4

2

4

X

Explosives

1.3, 1.6

*

*

*

4

2

2

4

3

3

4

4

4

2

4

2

2

X

Explosives

1.4

*

*

*

2

1

1

2

2

2

2

2

2

X

4

2

2

X

Flammable gases

2.1

4

4

2

X

X

X

2

1

2

2

2

2

X

4

2

1

X

Non-toxic, non-flammable gases

2.2

2

2

1

X

X

X

1

X

1

X

X

1

X

2

1

X

X

Toxic gases

2.3

2

2

1

X

X

X

2

X

2

X

X

2

X

2

1

X

X

Flammable liquids

3

4

4

2

2

1

2

X

X

2

2

2

2

X

3

2

X

X

Flammable solids (including self- reactive substances and solid desensitized explosives)

4.1

4

3

2

1

X

X

X

X

1

X

1

2

X

3

2

1

X

Substances liable to spontaneous combustion

4.2

4

3

2

2

1

2

2

1

X

1

2

2

1

3

2

1

X

Substances which, in contact with water, emit flammable gases

4.3

4

4

2

2

X

X

2

X

1

X

2

2

X

2

2

1

X

Oxidizing substances (agents)

5.1

4

4

2

2

X

X

2

1

2

2

X

2

1

3

1

2

X

Organic peroxides

5.2

4

4

2

2

1

2

2

2

2

2

2

X

1

3

2

2

X

Toxic substances

6.1

2

2

X

X

X

X

X

X

1

X

1

1

X

1

X

X

X

Infectious substances

6.2

4

4

4

4

2

2

3

3

3

2

3

3

1

X

3

3

X

Radioactive material

7

2

2

2

2

1

1

2

2

2

2

1

2

X

3

X

2

X

Corrosive substances

8

2

2

2

1

X

X

X

1

1

1

2

2

X

3

2

X

X

Miscellaneous dangerous substances and articles

9

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

X

 

The numbers and symbols in the table have the following meanings:

1   – “away from”

2   – “separated from”

3   – “separated by a complete compartment or hold from”

4   – “separated longitudinally by an intervening complete compartment or hold from”

X – the Dangerous Goods List has to be consulted to verify whether there are specific segregation provisions

*   – see 7.2.7.1 of this chapter for the segregation provisions between class 1 substances or articles

7.2.5 Segregation groups

7.2.5.1 For the purpose of segregation, dangerous goods having certain similar chemical properties have been grouped together in segregation groups as listed in 7.2.5.2. The entries allocated to these segregation groups are listed in 3.1.4.4. Where in the Dangerous Goods List entry in column 16b a particular segregation requirement refers to a group of substances, such as “acids”, the particular segregation requirement applies to the goods allocated to the respective segregation group.

7.2.5.2 Segregation groups referred to in the Dangerous Goods List:

.1       acids

.2       ammonium compounds

.3       bromates

.4       chlorates

.5       chlorites

.6       cyanides

.7       heavy metals and their salts (including their organometallic compounds)

.8       hypochlorites

.9       lead and its compounds

.10     liquid halogenated hydrocarbons

.11     mercury and mercury compounds

.12     nitrites and their mixtures

.13     perchlorates

.14     permanganates

.15     powdered metals

.16     peroxides

.17     azides

.18     alkalis.

7.2.5.3 It is recognized that not all substances, mixtures, solutions or preparations falling within a segregation group are listed in the IMDG Code by name. These are shipped under N.O.S. entries. Although these N.O.S. entries are not themselves listed in the segregation groups (see 3.1.4.4), the consignor shall decide whether inclusion under the segregation group is appropriate and, if so, shall mention that fact in the transport document (see 5.4.1.5.11).

7.2.5.4 The segregation groups in this Code do not cover substances which fall outside the classification criteria of this Code. It is recognized that some non-hazardous substances have similar chemical properties as substances listed in the segregation groups. A consignor or the person responsible for packing the goods into a cargo transport unit who does have knowledge of the chemical properties of such non-dangerous goods may decide to implement the segregation requirements of a related segregation group on a voluntary basis.

7.2.6 Special segregation provisions and exemptions

7.2.6.1 Notwithstanding 7.2.3.3 and 7.2.3.4, substances of the same class may be stowed together without regard to segregation required by secondary hazards (subsidiary risk label(s)), provided that the substances do not react dangerously with each other and cause:

.1       combustion and/or evolution of considerable heat;

.2       evolution of flammable, toxic or asphyxiant gases;

.3       the formation of corrosive substances; or

.4       the formation of unstable substances.

7.2.6.2 Where the Dangerous Goods List specifies that “segregation as for class ...” applies, the segregation provisions applicable to that class in 7.2.4 shall be applied. However, for the purposes of interpreting 7.2.6.1, which permits substances of the same class to be stowed together provided they do not react dangerously with each other, the segregation provisions of the class as represented by the primary hazard class in the Dangerous Goods List shall be applied.

For example:

UN 2965 – BORON TRIFLUORIDE DIMETHYL ETHERATE, class 4.3

The Dangerous Goods List entry specifies “segregation as for class 3, but “away from” classes 4.1 and 8”.

For the purposes of establishing the segregation provisions applicable in 7.2.4, the class 3 column shall be consulted.

This substance may be stowed together with other class 4.3 substances where they do not react dangerously with each other, see 7.2.6.1.

7.2.6.3 No segregation needs to be applied:

.1       between dangerous goods of different classes which comprise the same substance but vary only in their water content, such as sodium sulphide in classes 4.2 and 8 or for class 7 if the difference is due to quantity only; and

.2       between dangerous goods which belong to a group of substances of different classes but for which scientific evidence exists that they do not react dangerously when in contact with each other. Substances within the same table shown below are compatible with one another.

Table 7.2.6.3.1

UN

Proper shipping name

Class

Subsidiary risk(s)

Packing group

2014

HYDROGEN PEROXIDE, AQUEOUS SOLUTION with not less than 20% but not more than 60% hydrogen peroxide (stabilized as necessary)

5.1

8

II

2984

HYDROGEN PEROXIDE, AQUEOUS SOLUTION with not less than 8% but less than 20% hydrogen peroxide (stabilized as necessary)

5.1

 

III

3105

ORGANIC PEROXIDE TYPE D, LIQUID (peroxyacetic acid, type D, stabilized)

5.2

8

 

3107

ORGANIC PEROXIDE TYPE E, LIQUID (peroxyacetic acid, type E, stabilized)

5.2

8

 

3109

ORGANIC PEROXIDE TYPE F, LIQUID (peroxyacetic acid, type F, stabilized)

5.2

8

 

3149

HYDROGEN PEROXIDE AND PEROXYACETIC ACID, MIXTURE with acid(s), water and not more than 5% peroxyacetic acid, STABILIZED

5.1

8

II

 

Table 7.2.6.3.2

UN

Proper shipping name

Class

Subsidiary risk(s)

Packing group

1295

TRICHLOROSILANE

4.3

3/8

I

1818

SILICON TETRACHLORIDE

8

II

2189

DICHLOROSILANE

2.3

2.1/8

 

Table 7.2.6.3.3

UN

Proper shipping name

Class

Subsidiary risk(s)

Packing group

3391

ORGANOMETALLIC SUBSTANCE, SOLID, PYROPHORIC

4.2

 

I

3392

ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC

4.2

 

I

3393

ORGANOMETALLIC SUBSTANCE, SOLID, PYROPHORIC, WATER-REACTIVE

4.2

4.3

I

3394

ORGANOMETALLIC SUBSTANCE, LIQUID, PYROPHORIC, WATER-REACTIVE

4.2

4.3

I

3395

ORGANOMETALLIC SUBSTANCE, SOLID, WATER-REACTIVE

4.3

 

I, II, III

3396

ORGANOMETALLIC SUBSTANCE, SOLID, WATER REACTIVE, FLAMMABLE

4.3

4.1

I, II, III

3397

ORGANOMETALLIC SUBSTANCE, SOLID, WATER REACTIVE, SELF-HEATING

4.3

4.2

I, II, III

3398

ORGANOMETALLIC SUBSTANCE, LIQUID, WATER REACTIVE

4.3

 

I, II, III

3399

ORGANOMETALLIC SUBSTANCE, LIQUID, WATER REACTIVE, FLAMMABLE

4.3

3

I, II, III

3400

ORGANOMETALLIC SUBSTANCE, SOLID , SELF-HEATING

4.2

 

II, III

 

7.2.6.4 Notwithstanding the provisions of 7.2.5, substances of class 8, packing group II or III, that would otherwise be required to be segregated from one another due to the provisions pertaining to segregation groups as identified by an entry in column 16b of the Dangerous Goods List indicating “away from” or “separated from” “acids” or “away from” or “separated from” “alkalis”, may be transported in the same cargo transport unit, whether in the same packaging or not, provided:

.1       the substances comply with the provisions of 7.2.6.1;

.2       the package does not contain more than 30 L for liquids or 30 kg for solids;

.3       the transport document includes the statement required by 5.4.1.5.11.3; and

.4       a copy of the test report that verifies that the substances do not react dangerously with each other shall be provided if requested by the competent authority.

7.2.7 Segregation of goods of class 1

7.2.7.1 Segregation between goods of class 1

7.2.7.1.1 Goods of class 1 may be stowed within the same compartment or hold, or closed cargo transport unit as indicated in 7.2.7.1.4. In other cases, they shall be stowed in separate compartments or holds, or closed cargo transport units.

7.2.7.1.2 When goods requiring different stowage arrangements are permitted by 7.2.7.1.4 to be transported in the same compartment or hold, or closed cargo transport unit, the appropriate stowage arrangement shall conform to the most stringent provisions for the entire load.

7.2.7.1.3 Where a mixed load of different divisions is transported within the same compartment or hold, or closed cargo transport unit, the entire load shall be treated as if belonging to the hazard division in the order 1.1 (most dangerous), 1.5, 1.2, 1.3, 1.6 and 1.4 (least dangerous) and the stowage arrangement shall conform to the most stringent provisions for the entire load.

7.2.7.1.4 Permitted mixed stowage for goods of class 1

Compatibility group

A

B

C

D

E

F

G

H

J

K

L

N

S

A

X

 

 

 

 

 

 

 

 

 

 

 

 

B

 

X

 

 

 

 

 

 

 

 

 

 

X

C

 

 

X

X6

X6

 

X1

 

 

 

 

X4

X

D

 

 

X6

X

X6

 

X1

 

 

 

 

X4

X

E

 

 

X6

X6

X

 

X1

 

 

 

 

X4

X

F

 

 

 

 

 

X

 

 

 

 

 

 

X

G

 

 

X1

X1

X1

 

X

 

 

 

 

 

X

H

 

 

 

 

 

 

 

X

 

 

 

 

X

J

 

 

 

 

 

 

 

 

X

 

 

 

X

K

 

 

 

 

 

 

 

 

 

X

 

 

X

L

 

 

 

 

 

 

 

 

 

 

X2

 

 

N

 

 

X4

X4

X4

 

 

 

 

 

 

X3

X5

S

 

X

X

X

X

X

X

X

X

X

 

X5

X

 

“X” indicates that goods of the corresponding compatibility groups may be stowed in the same compartment, hold, or closed cargo transport unit.

 

Notes

1    Explosive articles in compatibility group G (other than fireworks and those requiring special stowage) may be stowed with explosive articles of compatibility groups C, D and E provided no explosive substances are transported in the same compartment or hold, or closed cargo transport unit.

2    A consignment of one type in compatibility group L shall only be stowed with a consignment of the same type within compatibility group L.

3    Different types of articles of Division 1.6, compatibility group N, may only be transported together when it is proven that there is no additional risk of sympathetic detonation between the articles. Otherwise they shall be treated as division 1.1.

4    When articles of compatibility group N are transported with articles or substances of compatibility groups C, D or E, the goods of compatibility group N shall be treated as compatibility group D.

5    When articles of compatibility group N are transported together with articles or substances of compatibility group S, the entire load shall be treated as compatibility group N.

6    Any combination of articles in compatibility groups C, D and E shall be treated as compatibility group E. Any combination of substances in compatibility groups C and D shall be treated as the most appropriate compatibility group shown in 2.1.2.3, taking into account the predominant characteristics of the combined load. This overall classification code shall be displayed on any label or placard placed on a unit load or closed cargo transport unit as prescribed in 5.2.2.2.2.

 

7.2.7.1.5 Closed cargo transport units carrying different goods of class 1 do not require segregation from each other provided 7.2.7.1.4 authorizes the goods to be transported together. Where this is not permitted, closed cargo transport unit shall be “separated from” one another.

7.2.7.2 Segregation from goods of other classes

7.2.7.2.1 Notwithstanding the segregation provisions of this chapter, AMMONIUM NITRATE (UN 1942), AMMONIUM NITRATE FERTILIZERS (UN 2067), alkali metal nitrates (e.g. UN 1486) and alkaline earth metal nitrates (e.g. UN 1454) may be stowed together with blasting explosives (except EXPLOSIVE, BLASTING, TYPE C, UN 0083) provided the aggregate is treated as blasting explosives under class 1.

Note: Alkali metal nitrates include caesium nitrate (UN 1451), lithium nitrate (UN 2722), potassium nitrate (UN 1486), rubidium nitrate (UN 1477) and sodium nitrate (UN 1498). Alkaline earth metal nitrates include barium nitrate (UN 1446), beryllium nitrate (UN 2464), calcium nitrate (UN 1454), magnesium nitrate (UN 1474) and strontium nitrate (UN 1507).

7.2.8 Segregation codes

The segregation codes given in column 16b of the Dangerous Goods List are as specified below:

Segregation code

Description

SG1

For packages carrying a subsidiary risk label of class 1, segregation as for class 1, division 1.3.

SG2

Segregation as for class 1.2G.

SG3

Segregation as for class 1.3G.

SG4

Segregation as for class 2.1.

SG5

Segregation as for class 3.

SG6

Segregation as for class 5.1.

SG7

Stow “away from” class 3.

SG8

Stow “away from” class 4.1.

SG9

Stow “away from” class 4.3.

SG10

Stow “away from” class 5.1.

SG11

Stow “away from” class 6.2.

SG12

Stow “away from” class 7.

SG13

Stow “away from” class 8.

SG14

Stow “separated from” class 1 except for division 1.4S.

SG15

Stow “separated from” class 3.

SG16

Stow “separated from” class 4.1.

SG17

Stow “separated from” class 5.1.

SG18

Stow “separated from” class 6.2.

SG19

Stow “separated from” class 7.

SG20

Stow “away from” acids.

SG21

Stow “away from” alkalis.

SG22

Stow “away from” ammonium salts.

SG23

Stow “away from” animal or vegetable oils.

SG24

Stow “away from” azides.

SG25

Stow “separated from” goods of classes 2.1 and 3.

SG26

In addition: from goods of classes 2.1 and 3 when stowed on deck of a containership a minimum distance of two container spaces athwartship shall be maintained, when stowed on ro-ro ships a distance of 6 m athwartship shall be maintained.

SG27

Stow “away from” explosives containing chlorates or perchlorates.

SG28

Stow “away from” ammonium compounds and explosives containing ammonium compounds or salts.

SG29

Segregation from foodstuffs as in 7.3.4.2.2, 7.6.3.1.2 or 7.7.3.7.

SG30

Stow “away from” heavy metals and their salts.

SG31

Stow “away from” lead and its compounds.

SG32

Stow “away from” liquid halogenated hydrocarbons.

SG33

Stow “away from” powdered metals.

SG34

When containing ammonium compounds, “away from” chlorates or perchlorates and explosives containing chlorates or perchlorates.

SG35

Stow “separated from” acids.

SG36

Stow “separated from” alkalis.

SG37

Stow “separated from” ammonia.

SG38

Stow “separated from” ammonium compounds.

SG39

Stow “separated from” ammonium compounds other than AMMONIUM PERSULPHATE (UN 1444).

SG40

Stow “separated from” ammonium compounds other than mixtures of ammonium persulphates and/or potassium persulphates and/or sodium persulphates.

SG41

Stow “separated from” animal or vegetable oil.

 


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