IMDG Code. Part 4 (2018)

THE INTERNATIONAL MARITIME DANGEROUS GOODS (IMDG) CODE

AMENDMENT 38-16

 (adopted on 13 May 2016 by MSC.406(96))

enter into force on 1 January 2018

 

PART 4

PACKING AND TANK PROVISIONS

 

Chapter 4.1. Use of packagings, including intermediate bulk containers (IBCs) and large packagings

4.1.0 Definitions

Effectively closed: liquid-tight closure.

Hermetically sealed: vapour-tight closure.

Securely closed: so closed that dry contents cannot escape during normal handling; the minimum provisions for any closure.

4.1.1 General provisions for the packing of dangerous goods in packagings, including IBCs and large packagings

Note: For the packing of goods of classes 2, 6.2 and 7, the general provisions of this section only apply as indicated in 4.1.8.2 (class 6.2), 4.1.9.1.5 (class 7) and in the applicable packing instructions of 4.1.4 (P201 and LP02 for class 2 and P620, P621, P650, IBC620 and LP621 for class 6.2).

4.1.1.1 Dangerous goods shall be packed in good quality packagings, including IBCs and large packagings, which shall be strong enough to withstand the shocks and loadings normally encountered during transport, including trans-shipment between cargo transport units and between cargo transport units and warehouses as well as any removal from a pallet or overpack for subsequent manual or mechanical handling. Packagings, including IBCs and large packagings, shall be constructed and closed so as to prevent any loss of contents when prepared for transport which may be caused under normal conditions of transport, by vibration, or by changes in temperature, humidity or pressure (resulting from altitude, for example). Packagings, including IBCs and large packagings, shall be closed in accordance with the information provided by the manufacturer. No dangerous residue shall adhere to the outside of packages, IBCs and large packagings during transport. These provisions apply, as appropriate, to new, reused, reconditioned or remanufactured packagings, and to new, reused, repaired or remanufactured IBCs, and to new, reused or remanufactured large packagings.

4.1.1.2 Parts of packagings, including IBCs and large packagings, which are in direct contact with dangerous goods:

.1       shall not be affected or significantly weakened by those dangerous goods; and

.2       shall not cause a dangerous effect, such as catalysing a reaction or reacting with the dangerous goods; and

.3       shall not allow permeation of the dangerous goods that could constitute a danger under normal conditions of transport.

Where necessary, they shall be provided with a suitable inner coating or treatment.

4.1.1.3 Unless otherwise provided elsewhere in this Code, each packaging, including IBCs and large packagings, except inner packagings, shall conform to a design type successfully tested in accordance with the provisions of 6.1.5, 6.3.5, 6.5.6 or 6.6.5, as applicable. However, IBCs manufactured before 1 January 2011 and conforming to a design type which has not passed the vibration test of 6.5.6.13 or which was not required to meet the criteria of 6.5.6.9.5.4 at the time it was subjected to the drop test may still be used.

4.1.1.4 When filling packagings, including IBCs and large packagings, with liquids,* sufficient ullage (outage) shall be left to ensure that neither leakage nor permanent distortion of the packaging occurs as a result of an expansion of the liquid caused by temperatures likely to occur during transport. Unless specific provisions are prescribed, liquids shall not completely fill a packaging at a temperature of 55°C. However, sufficient ullage shall be left in an IBC to ensure that at the mean bulk temperature of 50°C it is not filled to more than 98% of its water capacity.

___________________________

*  With respect to ullage limits only, the provisions applicable for packagings for solid substances may be used if the viscous substance has an outflow time via a DIN-cup with a 4 mm diameter outlet exceeding 10 minutes at 20°C (corresponding to an outflow time via a Ford cup 4 of more than 690 seconds at 20°C, or to a viscosity of more than 2680 centistokes at 20°C).

  For a differing temperature, the maximum degree of filling may be determined as follows:

Degree of filling = 98/(1 + α (50 - tF)) per cent of the capacity of the IBC

In this formula α represents the mean coefficient of cubic expansion of the liquid substance between 15°C and 50°C; that is to say, for a maximum rise in the temperature of 35°C, “α” is calculated according to the formula:

α = d15 - d50 /(35 x d50) ,

where d15 and d50 are the relative densities of the liquid at 15°C and 50°C and tF is the mean temperature of the liquid at the time of filling.

4.1.1.4.1 For air transport, packagings intended to contain liquids shall also be capable of withstanding a pressure differential without leakage as specified in the international regulations for air transport.

4.1.1.5 Inner packagings shall be packed in an outer packaging in such a way that, under normal conditions of transport, they cannot break, be punctured or leak their contents into the outer packaging. Inner packagings containing liquids shall be packaged with their closures upward and placed within outer packagings consistent with the orientation marks prescribed in 5.2.1.7.1 of this Code. Inner packagings that are liable to break or be punctured easily, such as those made of glass, porcelain or stoneware or of certain plastics materials, etc., shall be secured in outer packagings with suitable cushioning material. Any leakage of the contents shall not substantially impair the protective properties of the cushioning material or of the outer packaging.

4.1.1.5.1 Where an outer packaging of a combination packaging or a large packaging has been successfully tested with different types of inner packagings, a variety of such different inner packagings may also be assembled in this outer packaging or large packagings. In addition, provided an equivalent level of performance is maintained, the following variations in inner packagings are allowed without further testing of the package:

.1       Inner packagings of equivalent or smaller size may be used provided:

   the inner packagings are of similar design to the tested inner packagings (such as shape – round, rectangular, etc.);

   the material of construction of inner packagings (glass, plastics, metal, etc.) offers resistance to impact and stacking forces equal to or greater than that of the originally tested inner packaging;

   the inner packagings have the same or smaller openings and the closure is of similar design (such as screw cap, friction lid, etc.);

   sufficient additional cushioning material is used to take up void spaces and to prevent significant movement of the inner packagings;

   inner packagings are oriented within the outer packaging in the same manner as in the tested package; and

.2       A lesser number of the tested inner packagings or of the alternative types of inner packagings identified in .1 above may be used, provided sufficient cushioning is added to fill the void space(s) and to prevent significant movement of the inner packagings.

4.1.1.5.2 Use of supplementary packagings within an outer packaging (e.g. an intermediate packaging or a receptacle inside a required inner packaging) additional to what is required by the packing instructions is authorized provided all relevant requirements are met, including those of 4.1.1.3, and, if appropriate, suitable cushioning is used to prevent movement within the packaging.

4.1.1.5.3 Cushioning and absorbent material shall be inert and suited to the nature of the contents.

4.1.1.5.4 The nature and the thickness of the outer packagings shall be such that friction during transport does not generate any heating likely to alter dangerously the chemical stability of the contents.

4.1.1.6 Dangerous goods shall not be packed together in the same outer packaging, or in large packagings, with dangerous or other goods if they react dangerously with each other and cause:

.1       combustion and/or evolution of considerable heat;

.2       evolution of flammable, toxic or asphyxiant gases;

.3       the formation of corrosive substances; or

.4       the formation of unstable substances.

4.1.1.7 The closures of packagings containing wetted or diluted substances shall be such that the percentage of liquid (water, solvent or phlegmatizer) does not fall below the prescribed limits during transport.

4.1.1.7.1 Where two or more closure systems are fitted in series on an IBC, that nearest to the substance being transported shall be closed first.

4.1.1.7.2 Unless otherwise specified in the Dangerous Goods List, packages containing substances which:

.1       evolve flammable gases or vapour;

.2       may become explosive if allowed to dry;

.3       evolve toxic gases or vapour;

.4       evolve corrosive gases or vapour; or

.5       may react dangerously with the atmosphere should be hermetically sealed.

4.1.1.8 Where pressure may develop in a package by the emission of gas from the contents (as a result of temperature increase or other causes), the packaging or IBC may be fitted with a vent provided that the gas emitted will not cause danger on account of its toxicity, its flammability, the quantity released, etc.

A venting device shall be fitted if dangerous overpressure may develop due to normal decomposition of substances. The vent shall be so designed that, when the packaging or IBC is in the attitude in which it is intended to be transported, leakages of liquid and the penetration of foreign substances are prevented under normal conditions of transport.

4.1.1.8.1 Liquids may only be filled into inner packagings which have an appropriate resistance to internal pressure that may be developed under normal conditions of transport.

4.1.1.9 New, remanufactured or re-used packagings, including IBCs and large packagings, or reconditioned packagings and repaired or routinely maintained IBCs shall be capable of passing the tests prescribed in 6.1.5, 6.3.5, 6.5.6 or 6.6.5, as applicable. Before being filled and handed over for transport, every packaging, including IBCs and large packagings, shall be inspected to ensure that it is free from corrosion, contamination or other damage and every IBC shall be inspected with regard to the proper functioning of any service equipment. Any packaging which shows signs of reduced strength as compared with the approved design type shall no longer be used or shall be so reconditioned that it is able to withstand the design type tests. Any IBC which shows signs of reduced strength as compared with the tested design type shall no longer be used or shall be so repaired or routinely maintained that it is able to withstand the design type tests.

4.1.1.10 Liquids shall be filled only into packagings, including IBCs, which have an appropriate resistance to the i nternal pressure that may develop under normal conditions of transport. As the vapour pressure of low-boiling-point liquids is usually high, the strength of receptacles for these liquids shall be sufficient to withstand, with an ample factor of safety, the internal pressure likely to be generated. Packagings and IBCs marked with the hydraulic test pressure prescribed in 6.1.3.1(d) and 6.5.2.2.1, respectively, shall be filled only with a liquid having a vapour pressure:

.1       such that the total gauge pressure in the packaging or IBC (i.e. the vapour pressure of the filling substance plus the partial pressure of air or other inert gases, less 100 kPa) at 55°C, determined on the basis of a maximum degree of filling in accordance with 4.1.1.4 and a filling temperature of 15°C, will not exceed two thirds of the marked test pressure; or

.2       at 50°C, less than four sevenths of the sum of the marked test pressure plus 100 kPa; or

.3       at 55°C, less than two thirds of the sum of the marked test pressure plus 100 kPa.

IBCs intended for the transport of liquids shall not be used to carry liquids having a vapour pressure of more than 110 kPa (1.1 bar) at 50°C or 130 kPa (1.3 bar) at 55°C.

Examples of required marked test pressures for packagings, including IBCs, calculated as in 4.1.1.10.3

UN No.

Name

Class

Packing group

Vp55 (kPa)

Vp55×1.5 (kPa)

(Vp55×1.5) minus 100 (kPa)

Required minimum test pressure (gauge) under 6.1.5.5.4.3 (kPa)

Minimum test pressure (gauge) to be marked on the packaging (kPa)

2056

Tetrahydrofuran

3

I

70

105

5

100

100

2247

n-Decane

3

II

1.4

2.1

-97.9

100

100

1593

Dichloromethane

6.1

III

164

246

146

146

150

1155

Diethyl ether

3

I

199

299

199

199

250

 

Note 1: For pure liquids, the vapour pressure at 55°C (Vp55) can often be obtained from scientific tables.

Note 2: The table refers to the use of 4.1.1.10.3 only, which means that the marked test pressure shall exceed 1.5 times the vapour pressure at 55°C less 100 kPa. When, for example, the test pressure for n-decane is determined according to 6.1.5.5.4.1, the minimum marked test pressure may be lower.

Note 3: For diethyl ether, the required minimum test pressure under 6.1.5.5.5 is 250 kPa.

4.1.1.11 Empty packagings, including IBCs and large packagings, that have contained a dangerous substance shall be treated in the same manner as is required by this Code for a filled packaging, unless adequate measures have been taken to nullify any hazard.

4.1.1.12 Every packaging as specified in chapter 6.1 intended to contain liquids shall successfully undergo a suitable leakproofness test. This test is part of a quality assurance programme as stipulated in 6.1.1.3 which shows the capability of meeting the appropriate test level indicated in 6.1.5.4.4:

.1       before it is first used for transport;

.2       after remanufacturing or reconditioning of any packaging, before it is re-used for transport.

For this test, the packaging need not have its closures fitted. The inner receptacle of a composite packaging may be tested without the outer packaging, provided the test results are not affected. This test is not necessary for inner packagings of combination packagings or large packagings.

4.1.1.13 Packagings, including IBCs, used for solids which may become liquid at temperatures likely to be encountered during transport shall also be capable of containing the substance in the liquid state.

4.1.1.14 Packagings, including IBCs, used for powdery or granular substances shall be sift-proof or shall be provided with a liner.

4.1.1.15 For plastics drums and jerricans, rigid plastics IBCs and composite IBCs with plastics inner receptacles, unless otherwise approved by the competent authority, the period of use permitted for the transport of dangerous substances shall be five years from the date of manufacture of the receptacles, except where a shorter period of use is prescribed because of the nature of the substance to be transported.

4.1.1.16 Where ice is used as a coolant it shall not affect the integrity of the packaging.

4.1.1.17 Explosives, self-reactive substances and organic peroxides

Unless specific provision to the contrary is made in this Code, the packagings, including IBCs and large packagings, used for goods of class 1, self-reactive substances of class 4.1 and organic peroxides of class 5.2 shall comply with the provisions for the medium danger group (packing group II).

4.1.1.18 Use of salvage packagings and large salvage packagings

4.1.1.18.1 Damaged, defective, leaking or non-conforming packages, or dangerous goods that have spilled or leaked may be transported in salvage packagings mentioned in 6.1.5.1.11 and 6.6.5.1.9. This does not prevent the use of a larger size packaging or large packaging of appropriate type and performance level and under the conditions of 4.1.1.18.2 and 4.1.1.18.3.

4.1.1.18.2 Appropriate measures shall be taken to prevent excessive movement of the damaged or leaking packages within a salvage packaging. When the salvage packaging contains liquids, sufficient inert absorbent material shall be added to eliminate the presence of free liquid.

4.1.1.18.3 Appropriate measures shall be taken to ensure there is no dangerous build-up of pressure.

4.1.1.19 Use of salvage pressure receptacles

4.1.1.19.1 In the case of damaged, defective, leaking or non-conforming pressure receptacles, salvage pressure receptacles according to 6.2.3 may be used.

Note: A salvage pressure receptacle may be used as an overpack in accordance with 5.1.2. When used as an overpack, marks shall be in accordance with 5.1.2.1 instead of 5.2.1.3.

4.1.1.19.2 Pressure receptacles shall be placed in salvage pressure receptacles of suitable size. The maximum size of the placed pressure receptacle is limited to a water capacity of 1,000 litres. More than one pressure receptacle may be placed in the same salvage pressure receptacle only if the contents are known and do not react dangerously with each other (see 4.1.1.6). In this case the total sum of water capacities of the placed pressure receptacles shall not exceed 1,000 litres. Measures shall be taken to prevent movement of the pressure receptacles within the salvage pressure receptacle, e.g. by partitioning, securing or cushioning.

4.1.1.19.3 A pressure receptacle may only be placed in a salvage pressure receptacle if:

.1       the salvage pressure receptacle is in accordance with 6.2.3.5 and a copy of the approval certificate is available;

.2       parts of the salvage pressure receptacle which are, or are likely to be in direct contact with the dangerous goods will not be affected or weakened by those dangerous goods and will not cause a dangerous effect (e.g. catalysing reaction or reacting with the dangerous goods); and

.3       the contents of the contained pressure receptacle(s) is limited in pressure and volume so that if totally discharged into the salvage pressure receptacle, the pressure in the salvage pressure receptacle at 65°C will not exceed the test pressure of the salvage pressure receptacle (for gases, see packing instruction in P200 (3) 4.1.4.1). The reduction of the useable water capacity of the salvage pressure receptacle, e.g. by any contained equipment and cushioning, shall be taken into account.

4.1.1.19.4 The proper shipping name, the UN number preceded by the letters “UN” and label(s) as required for packages in chapter 5.2 applicable to the dangerous goods inside the contained pressure receptacle(s) shall be applied to the salvage pressure receptacle for transport.

4.1.1.19.5 Salvage pressure receptacles shall be cleaned, purged and visually inspected internally and externally after each use. They shall be periodically inspected and tested in accordance with 6.2.1.6 at least once every five years.

4.1.1.20 During transport, packagings, including IBCs and large packagings, shall be securely fastened to or contained within the cargo transport unit, so that lateral or longitudinal movement or impact is prevented and adequate external support is provided.

4.1.2 Additional general provisions for the use of IBCs

4.1.2.1 When IBCs are used for the transport of liquids with a flashpoint of 60°C (closed cup) or lower, or of powders liable to dust explosion, measures shall be taken to prevent a dangerous electrostatic discharge.

4.1.2.2.1 Every metal, rigid plastics and composite IBC shall be inspected and tested, as relevant, in accordance with 6.5.4.4 or 6.5.4.5:

.1       before it is put into service;

.2       thereafter at intervals not exceeding two and a half and five years, as appropriate; and

.3       after the repair or remanufacture, before it is re-used for transport.

4.1.2.2.2 An IBC shall not be filled and offered for transport after the date of expiry of the last periodic test or inspection. However, an IBC filled prior to the date of expiry of the last periodic test or inspection may be transported for a period not to exceed three months beyond the date of expiry of the last periodic test or inspection. In addition, an IBC may be transported after the date of expiry of the last periodic test or inspection:

.1       after emptying but before cleaning, for purposes of performing the required test or inspection prior to refilling; and

.2       unless otherwise approved by the competent authority, for a period not to exceed six months beyond the date of expiry of the last periodic test or inspection in order to allow the return of dangerous goods or residues for proper disposal or recycling. Reference to this exemption shall be entered in the transport document.

4.1.2.3 IBCs of type 31HZ2 when transporting liquids shall be filled to at least 80% of the volume of the outer casing and shall be transported in closed cargo transport units.

4.1.2.4 Except for routine maintenance of metal, rigid plastics, composite and flexible IBCs performed by the owner of the IBC, whose State and name or authorized symbol is durably marked on the IBC, the party performing routine maintenance shall durably mark the IBC near the manufacturer’s UN design type mark to show:

.1       the State in which the routine maintenance was carried out; and

.2       the name or authorized symbol of the party performing the routine maintenance.

4.1.3 General provisions concerning packing instructions

4.1.3.1 Packing instructions applicable to dangerous goods of classes 1 to 9 are specified in 4.1.4. They are subdivided in three subsections depending on the type of packagings to which they apply:

 subsection 4.1.4.1    f or packagings other than IBCs and large packagings; these packing instructions are designated by an alphanumeric code comprising the letter “P”;

 subsection 4.1.4.2    f or IBCs; these are designated by an alphanumeric code comprising the letters “IBC”;

 subsection 4.1.4.3    for large packagings; these are designated by an alphanumeric code comprising the letters “LP”.

Generally, packing instructions specify that the general provisions of 4.1.1, 4.1.2 and/or 4.1.3, as appropriate, are applicable. They may also require compliance with the special provisions of 4.1.5, 4.1.6, 4.1.7, 4.1.8 or 4.1.9 when appropriate. Special packing provisions may also be specified in the packing instruction for individual substances or articles. They are also designated by an alphanumeric code comprising the letters:

 “PP”    for packagings other than IBCs and large packagings

 “B”      for IBCs

 “L”      for large packagings.

Unless otherwise specified, each packaging shall conform to the applicable provisions of part 6. Generally, packing instructions do not provide guidance on compatibility and the user shall not select a packaging without checking that the substance is compatible with the packaging material selected (such as, most fluorides are unsuitable for glass receptacles). Where glass receptacles are permitted in the packing instructions, porcelain, earthenware and stoneware packagings are also allowed.

4.1.3.2 Column 8 of the Dangerous Goods List shows for each article or substance the packing instruction(s) that shall be used. Column 9 indicates the special packing provisions applicable to specific substances or articles.

4.1.3.3 Each packing instruction shows, where applicable, the acceptable single and combination packagings. For combination packagings, the acceptable outer packagings, inner packagings and, when applicable, the maximum quantity permitted in each inner or outer packaging are shown. Maximum net mass and maximum capacity are as defined in 1.2.1.

4.1.3.4 The following packagings shall not be used when the substances being transported are liable to become liquid during transport:

Packagings

 Drums:            1D and 1G

 Boxes:             4C1, 4C2, 4D, 4F, 4G and 4H1

 Bags:               5L1, 5L2, 5L3, 5H1, 5H2, 5H3, 5H4, 5M1 and 5M2

 Composite:      6HC, 6HD1, 6HD2, 6HG1, 6HG2, 6PC, 6PD1, 6PD2, 6PG1, 6PG2 and 6PH1

Large packagings

Flexible plastics: 51H (outer packaging)

IBCs

For substances of packing group I:

 All types of IBCs

For substances of packing groups II and III:

 Wooden:         11C, 11D and 11F

 Fibreboard:     11G

 Flexible:           13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 and 13M2

 Composite:      11HZ2 and 21HZ2

4.1.3.5 Where the packing instructions in this chapter authorize the use of a particular type of packaging (such as 4G; 1A2), packagings bearing the same packaging identification code followed by the letters “V”, “U” or “W” marked in accordance with the provisions of part 6 (such as “4GV”, “4GU” or “4GW”; “1A2V”, “1A2U” or “1A2W”) may also be used under the same conditions and limitations applicable to the use of that type of packaging according to the relevant packing instructions. For example, a combination packaging marked with the packaging code “4GV” may be used whenever a combination packaging marked “4G” is authorized, provided the provisions in the relevant packing instruction regarding types of inner packagings and quantity limitations are respected.

4.1.3.6 Pressure receptacles for liquids and solids

4.1.3.6.1 Unless otherwise indicated in this Code, pressure receptacles conforming to:

.1       the applicable requirements of chapter 6.2; or

.2       the National or International standards on the design, construction, testing, manufacturing and inspection, as applied by the country in which the pressure receptacles are manufactured, provided that the provisions of 4.1.3.6 and 6.2.3.3 are met,

are authorized for the transport of any liquid or solid substance other than explosives, thermally unstable substances, organic peroxides, self-reactive substances, substances where significant pressure may develop by evolution of chemical reaction and radioactive material (unless permitted in 4.1.9).

This subsection is not applicable to the substances mentioned in 4.1.4.1, packing instruction P200, table 3.

4.1.3.6.2 Every design type of pressure receptacle shall be approved by the competent authority of the country of manufacture or as indicated in chapter 6.2.

4.1.3.6.3 Unless otherwise indicated, pressure receptacles having a minimum test pressure of 0.6 MPa shall be used.

4.1.3.6.4 Unless otherwise indicated, pressure receptacles may be provided with an emergency pressure relief device designed to avoid bursting in case of overfill or fire accidents.

Pressure receptacle valves shall be designed and constructed in such a way that they are inherently able to withstand damage without release of the contents or shall be protected from damage which could cause inadvertent release of the contents of the pressure receptacle, by one of the methods as given in 4.1.6.1.8.1 to 4.1.6.1.8.5.

4.1.3.6.5 The level of filling shall not exceed 95% of the capacity of the pressure receptacle at 50°C. Sufficient ullage (outage) shall be left to ensure that the pressure receptacle will not be liquid-full at a temperature of 55°C.

4.1.3.6.6 Unless otherwise indicated, pressure receptacles shall be subjected to a periodic inspection and test every five years. The periodic inspection shall include an external examination, an internal examination or alternative method as approved by the competent authority, a pressure test or equivalent effective non-destructive testing with the agreement of the competent authority, including an inspection of all accessories (e.g. tightness of valves, emergency relief valves or fusible elements). Pressure receptacles shall not be filled after they become due for periodic inspection and test but may be transported after the expiry of the time limit. Pressure receptacle repairs shall meet the requirements of 4.1.6.1.11.

4.1.3.6.7 Prior to filling, the filler shall perform an inspection of the pressure receptacle and ensure that the pressure receptacle is authorized for the substances to be transported and that the provisions of this Code have been met. Shut-off valves shall be closed after filling and remain closed during transport. The consignor shall verify that the closures and equipment are not leaking.

4.1.3.6.8 Refillable pressure receptacles shall not be filled with a substance different from that previously contained unless the necessary operations for change of service have been performed.

4.1.3.6.9 Marking of pressure receptacles for liquids and solids according to 4.1.3.6 (not conforming to the requirements of chapter 6.2) shall be in accordance with the requirements of the competent authority of the country of manufacturing.

4.1.3.7 Packagings, including IBCs and large packagings, not specifically authorized in the applicable packing instruction shall not be used for the transport of a substance or article unless specifically approved by the competent authority and provided:

.1       the alternative packaging complies with the general provisions of this chapter;

.2       when the packing instruction indicated in the Dangerous Goods List so specifies, the alternative packaging meets the provisions of part 6;

.3       the competent authority determines that the alternative packaging provides at least the same level of safety as if the substance were packed in accordance with a method specified in the particular packing instruction indicated in the Dangerous Goods List; and

.4       a copy of the competent authority approval accompanies each consignment or the transport document includes an indication that alternative packaging was approved by the competent authority.

Note: The competent authorities granting such approvals shall take action to amend the Code to include the provisions covered by the approval as appropriate.

4.1.3.8 Unpackaged articles other than class 1 articles

4.1.3.8.1 Where large and robust articles cannot be packaged in accordance with the requirements of chapter 6.1 or 6.6 and they have to be transported empty, uncleaned and unpackaged, the competent authority may approve such transport. In doing so, the competent authority shall take into account that:

.1       Large and robust articles shall be strong enough to withstand the shocks and loadings normally encountered during transport, including trans-shipment between cargo transport units and between cargo transport units and warehouses, as well as any removal from a pallet for subsequent manual or mechanical handling.

.2       All closures and openings shall be sealed so that there can be no loss of contents which might be caused under normal conditions of transport, by vibration, or by changes in temperature, humidity or pressure (resulting from altitude, for example). No dangerous residue shall adhere to the outside of the large and robust articles.

.3       Parts of large and robust articles, which are in direct contact with dangerous goods:

.1       shall not be affected or significantly weakened by those dangerous goods; and

.2       shall not cause a dangerous effect, e.g. catalysing a reaction or reacting with the dangerous goods.

.4       Large and robust articles containing liquids shall be stowed and secured to ensure that neither leakage nor permanent distortion of the article occurs during transport.

.5       They shall be fixed in cradles or crates or other handling devices in such a way that they will not become loose during normal conditions of transport.

4.1.3.8.2 Unpackaged articles approved by the competent authority in accordance with the provisions of 4.1.3.8.1 shall be subject to the consignment procedures of part 5. In addition the consignor of such articles shall ensure that a copy of any such approval is transported with the large and robust articles.

Note: A large and robust article may include flexible fuel containment systems, military equipment, machinery or equipment containing dangerous goods above the limited quantity thresholds.

4.1.3.9 Where, in 4.1.3.6 and in the individual packing instructions, cylinders and other pressure receptacles for gases are authorized for the transport of any liquid or solid substance, use is also authorized of cylinders and pressure receptacles of a kind normally used for gases which conform to the requirements of the competent authority of the country in which the cylinder or pressure receptacle is filled. Valves shall be suitably protected. Pressure receptacles with capacities of 1 L or less shall be packed in outer packagings constructed of suitable material of adequate strength and design in relation to the capacity of the packaging and its intended use and secured or cushioned so as to prevent significant movement within the outer packaging during normal conditions of transport.

4.1.4 List of packing instructions

4.1.4.1 Packing instructions concerning the use of packagings (except IBCs and large packagings)

P001                                                     PACKING INSTRUCTION (LIQUIDS)                                          P001

The following packagings are authorized provided the general provisions of 4.1.1 and 4.1.3 are met.

Combination packagings

Maximum capacity/net mass (see 4.1.3.3)

Inner packagings

Outer packagings

Packing group I

Packing group II

Packing group III

Glass                10 L

Plastics              30 L

Metal                 40 L

Drums

 

 

 

steel (1A1, 1A2)

75 kg

400 kg

400 kg

aluminium (1B1, 1B2)

75 kg

400 kg

400 kg

other metal (1N1, 1N2)

75 kg

400 kg

400 kg

plastics (1H1, 1H2)

75 kg

400 kg

400 kg

plywood (1D)

75 kg

400 kg

400 kg

fibre (1G)

75 kg

400 kg

400 kg

Boxes

steel (4A)

75 kg

400 kg

400 kg

aluminium (4B)

75 kg

400 kg

400 kg

other metal (4N)

75 kg

400 kg

400 kg

natural wood (4C1, 4C2)

75 kg

400 kg

400 kg

plywood (4D)

75 kg

400 kg

400 kg

reconstituted wood (4F)

75 kg

400 kg

400 kg

fibreboard (4G)

75 kg

400 kg

400 kg

expanded plastics (4H1)

40 kg

 60 kg

 60 kg

solid plastics (4H2)

75 kg

400 kg

400 kg

Jerricans

  steel (3A1, 3A2)

60 kg

120 kg

120 kg

aluminium (3B1, 3B2)

60 kg

120 kg

120 kg

plastics (3H1, 3H2)

30 kg

120 kg

120 kg

Single packagings

 

 

 

Drums

steel, non-removable head (1A1)

250 L

450 L

450 L

steel, removable head (1A2)

prohibited

250 L

250 L

aluminium, non-removable head (1B1)

250 L

450 L

450 L

aluminium, removable head (1B2)

prohibited

250 L

250 L

other metal, non-removable head (1N1)

250 L

450 L

450 L

other metal, removable head (1N2)

prohibited

250 L

250 L

plastics, non-removable head (1H1)

250 L*

450 L

450 L

plastics, removable head (1H2)

prohibited

250 L

250 L

Jerricans

  steel, non-removable head (3A1)

60 L

60 L

60 L

steel, removable head (3A2)

prohibited

60 L

60 L

aluminium, non-removable head (3B1)

60 L

60 L

60 L

aluminium, removable head (3B2)

prohibited

60 L

60 L

plastics, non-removable head (3H1)

60 L*

60 L

60 L

plastics, removable head (3H2)

prohibited

60 L

60 L

Composite packagings

Plastics receptacle in steel or aluminium drum (6HA1, 6HB1)

250 L

250 L

250 L

Plastics receptacle in fibre, plastics or plywood drum (6HG1, 6HH1, 6HD1)

120 L*

250 L

250 L

Plastics receptacle in steel or aluminium crate or box or plastics receptacle in wood, plywood, fibreboard or solid plastics box (6HA2, 6HB2, 6HC, 6HD2, 6HG2 or 6HH2)

60 L*

60 L

60 L

Glass receptacle in steel, aluminium, fibre, plywood, solid plastics or expanded plastics drum (6PA1, 6PB1, 6PG1, 6PD1, 6PH1 or 6PH2) or in a steel, aluminium, wood or fibreboard box or in a wickerwork hamper (6PA2, 6PB2, 6PC, 6PG2 or 6PD2)

60 L

60 L

60 L

Pressure receptacles, provided that the general provisions of 4.1.3.6 are met

*  Not permitted for class 3, packing group I.

P001                             PACKING INSTRUCTION (LIQUIDS) (continued)                           P001

Special packing provisions:

PP1   For UN Nos. 1133, 1210, 1263 and 1866 and for adhesives, printing inks, printing ink related materials, paints, paint related materials and resin solutions which are assigned to UN 3082, metal or plastics packagings for substances of packing groups II and III in quantities of 5 L or less per packaging are not required to meet the performance tests in chapter 6.1 when transported:

(a)  in palletized loads, a pallet box or a unit load device, such as individual packagings placed or stacked and secured by strapping, shrink- or stretch-wrapping or other suitable means to a pallet. For sea transport, the palletized loads, pallet boxes or unit load devices shall be firmly packed and secured in closed cargo transport units. On roll-on/roll-off ships the unit loads may be carried in vehicles other than closed vehicles provided they are securely fenced to the full height of the cargo carried; or

(b)  as an inner packaging of a combination packaging with a maximum net mass of 40 kg.

PP2    For UN 3065, wooden barrels with a maximum capacity of 250 L and which do not meet the provisions of chapter 6.1 may be used.

PP4    For UN 1774, packagings shall meet the packing group II performance level.

PP5    For UN 1204, packagings shall be so constructed that explosion is not possible by reason of increased internal pressure. Gas cylinders and gas receptacles shall not be used for these substances.

PP10 For UN 1791, for packing group II, the packaging shall be vented.

PP31 For UN Nos. 1131, 1553, 1693, 1694, 1699, 1701, 2478, 2604, 2785, 3148, 3183, 3184, 3185, 3186, 3187, 3188, 3398 (PG II and III), 3399 (PG II and III), 3413 and 3414, packagings shall be hermetically sealed.

PP33 For UN 1308, for packing groups I and II, only combination packagings with a maximum gross mass of 75 kg are allowed.

PP81 For UN 1790 with more than 60% but not more than 85% hydrogen fluoride and UN 2031 with more than 55% nitric acid, the permitted use of plastics drums and jerricans as single packagings shall be two years from their date of manufacture

PP93 For UN Nos. 3532 and 3534, packagings shall be designed and constructed to permit the release of gas or vapour to prevent a build-up of pressure that could rupture the packagings in the event of loss of stabilization.

 

P002                                                     PACKING INSTRUCTION (SOLIDS)                                           P002

The following packagings are authorized provided the general provisions of 4.1.1 and 4.1.3 are met.

Combination packagings

Maximum net mass (see 4.1.3.3)

Inner packagings

Outer packagings

Packing group I

Packing group II

Packing group III

Glass

10 kg

Drums

 

 

 

Plastics 1

30 kg

steel (1A1, 1A2)

125 kg

400 kg

400 kg

Metal

40 kg

aluminium (1B1, 1B2)

125 kg

400 kg

400 kg

Paper 1,2,3

50 kg

other metal (1N1, 1N2)

125 kg

400 kg

400 kg

Fibre 1,2,3

50 kg

plastics (1H1, 1H2)

125 kg

400 kg

400 kg

 

 

plywood (1D)

125 kg

400 kg

400 kg

 

 

fibre (1G)

125 kg

400 kg

400 kg

1 These inner pack be sift-proof.

2 These inner packagings shall not be used when the substances being transported may become liquid during transport.

3 Paper and fibre inner packagings shall not be used for substances of packing agings shall group I.

Boxes

steel (4A)

aluminium (4B)

other metal (4N)

natural wood (4C1)

natural wood with

            sift-proof walls (4C2)

plywood (4D)

reconstituted wood (4F)

fibreboard (4G)

expanded plastics (4H1)

solid plastics (4H2)

 

125 kg

125 kg

125 kg

125 kg

250 kg

 

125 kg

125 kg

75 kg

40 kg

125 kg

 

400 kg

400 kg

400 kg

400 kg

400 kg

 

400 kg

400 kg

400 kg

60 kg

400 kg

 

400 kg

400 kg

400 kg

400 kg

400 kg

 

400 kg

400 kg

400 kg

60 kg

400 kg

Jerricans

steel (3A1, 3A2)

aluminium (3B1, 3B2)

plastics (3H1, 3H2)

 

75 kg

75 kg

75 kg

 

120 kg

120 kg 1

20 kg

 

120 kg

120 kg

120 kg

Single packagings

 

 

 

Drums

steel (1A1 or 1A24)

400 kg

400 kg

400 kg

aluminium (1B1 or 1B24)

400 kg

400 kg

400 kg

metal, other than steel or aluminium (1N1 or 1N24)

400 kg

400 kg

400 kg

plastics (1H1 or 1H24)

400 kg

400 kg

400 kg

fibre (1G5)

400 kg

400 kg

400 kg

plywood (1D5)

4  These packagings shall not be used for substances of packing group I that may become liquid during transport (see 4.1.3.4).

5  These packagings shall not be used when the substances being transported may become liquid during transport (see 4.1.3.4).

400 kg

400 kg

400 kg

 

P002                                      PACKING INSTRUCTION (SOLIDS) (continued)                                      P002

The following packagings are authorized provided the general provisions of 4.1.1 and 4.1.3 are met.

 

Maximum net mass (see 4.1.3.3)

Single packagings (continued)

Packing group I

Packing group II

Packing group III

Jerricans steel (3A1 or 3A24)

120 kg

120 kg

120 kg

aluminium (3B1 or 3B24)

120 kg

120 kg

120 kg

plastics (3H1 or 3H24)

120 kg

120 kg

120 kg

Boxes

steel (4A)5

Not allowed

400 kg

400 kg

aluminium (4B)5

Not allowed

400 kg

400 kg

other metal (4N)5

Not allowed

400 kg

400 kg

natural wood (4C1)5

Not allowed

400 kg

400 kg

natural wood with sift-proof walls (4C2)5

Not allowed

400 kg

400 kg

plywood (4D)5

Not allowed

400 kg

400 kg

reconstituted wood (4F)5

Not allowed

400 kg

400 kg

fibreboard (4G)5

Not allowed

400 kg

400 kg

solid plastics (4H2)5

Not allowed

400 kg

400 kg

Bags

bags (5H3, 5H4, 5L3, 5M2)5

Not allowed

 50 kg

 50 kg

Composite packagings

Plastics receptacle in steel, aluminium, plywood, fibre or plastics drum (6HA1, 6HB1, 6HG15, 6HD15, or 6HH1)

400 kg

400 kg

400 kg

Plastics receptacle in steel or aluminium crate or box, wooden box, plywood box, fibreboard box or solid plastics box (6HA2, 6HB2, 6HC, 6HD25, 6HG25 or 6HH2)

 75 kg

 75 kg

 75 kg

Glass receptacle in steel, aluminium, plywood or fibre drum (6PA1, 6PB1, 6PD15 or 6PG15) or in steel, aluminium, wood, or fibreboard box or in wickerwork hamper (6PA2, 6PB2, 6PC, 6PG25 or 6PD25) or in solid or expanded plastics packaging (6PH2 or 6PH15)

4   These packagings shall not be used for substances of packing group I that may become liquid during transport (see 4.1.3.4).

 5 These packagings shall not be used when the substances being transported may become liquid during transport (see 4.1.3.4).

 75 kg

 75 kg

 75 kg

Pressure receptacles, provided that the general provisions of 4.1.3.6 are met.

Special packing provisions:

PP7      For UN 2000, celluloid may be transported unpacked on pallets, wrapped in plastic film and secured by appropriate means, such as steel bands, as a single commodity in closed cargo transport units. Each pallet shall not exceed 1000 kg.

PP8      For UN 2002, packagings shall be so constructed that explosion is not possible by reason of increased internal pressure. Gas cylinders and gas receptacles shall not be used for these substances.

PP9      For UN Nos. 3175, 3243 and 3244, packagings shall conform to a design type that has passed a leakproofness test at the packing group II performance level. For UN 3175 the leakproofness test is not required when the liquids are fully absorbed in solid material contained in sealed bags.

PP11    For UN 1309, packing group III, and UN Nos. 1361 and 1362, 5M1 bags are allowed if they are overpacked in plastic bags and are wrapped in shrink or stretch wrap on pallets.

PP12    For UN Nos. 1361, 2213 and 3077, 5H1, 5L1 and 5M1 bags are allowed when transported in closed cargo transport units.

PP13    For articles classified under UN 2870, only combination packagings meeting the packing group I performance level are authorized.

PP14    For UN Nos. 2211, 2698 and 3314, packagings are not required to meet the performance tests in chapter 6.1.

PP15    For UN Nos. 1324 and 2623, packagings shall meet the packing group III performance level.

PP20    For UN 2217, any sift-proof, tearproof receptacle may be used.

PP30    For UN 2471, paper or fibre inner packagings are not permitted.

PP31    For UN Nos. 1362, 1463, 1565, 1575, 1626, 1680, 1689, 1698, 1868, 1889, 1932, 2471, 2545, 2546, 2881, 3048, 3088, 3170, 3174, 3181, 3182, 3189, 3190, 3205, 3206, 3341, 3342, 3448, 3449 and 3450, packagings shall be hermetically sealed.

PP34    For UN 2969 (as whole beans), 5H1, 5L1 and 5M1 bags are permitted.

PP37    For UN Nos. 2590 and 2212, 5M1 bags are permitted. All bags of any type shall be transported in closed cargo transport units or be placed in closed rigid overpacks.

PP38    For UN 1309, bags are permitted only in closed cargo transport units or as unit loads.

PP84    For UN 1057, rigid outer packagings meeting the packing group II performance level shall be used. The packagings shall be designed and constructed and arranged to prevent movement, inadvertent ignition of the devices or inadvertent release of flammable gas or liquid.

PP85    For UN Nos. 1748, 2208, 2880, 3485, 3486 and 3487, bags are not allowed.

PP92    For UN Nos. 3531 and 3533, packagings shall be designed and constructed to permit the release of gas or vapour to prevent a build-up of pressure that could rupture the packagings in the event of loss of stabilization.

PP100 For UN numbers 1309, 1323, 1333, 1376, 1435, 1449, 1457, 1472, 1476, 1483, 1509, 1516, 1567, 1869, 2210, 2858, 2878, 2968, 3089, 3096 and 3125, flexible, fibreboard or wooden packagings shall be sift-proof and water-resistant or shall be fitted with a sift-proof and water-resistant liner.

 

P003                                                      PACKING INSTRUCTION                                               P003

Dangerous goods shall be placed in suitable outer packagings. The packagings shall meet the provisions of 4.1.1.1, 4.1.1.2, 4.1.1.4, 4.1.1.8 and 4.1.3 and be so designed that they meet the construction provisions of 6.1.4. Outer packagings constructed of suitable material, and of adequate strength and design in relation to the packaging capacity and its intended use, shall be used. Where this packing instruction is used for the transport of articles or inner packagings of combination packagings, the packaging shall be designed and constructed to prevent inadvertent discharge of articles during normal conditions of transport.

Special packing provisions:

PP16    For UN 2800, batteries shall be protected from short circuit within the packagings.

PP17    For UN 2037, packages shall not exceed 55 kg net mass for fibreboard packagings or 125 kg net mass for other packagings.

PP18    For UN 1845, packagings shall be designed and constructed to permit the release of carbon dioxide gas to prevent a build-up of pressure that could rupture the packagings.

PP19    For UN Nos. 1327, 1364, 1365, 1856 and 3360, transport as bales is authorized.

PP20    For UN Nos. 1363, 1386, 1408 and 2793, any sift-proof, tearproof receptacle may be used.

PP32    UN Nos. 2857 and 3358 may be transported unpackaged, in crates or in appropriate overpacks.

PP90    For UN 3506, sealed inner liners or bags of strong leakproof and puncture resistant material impervious to mercury which will prevent escape of the substance from the package irrespective of the position of the package shall be used.

PP91    For UN 1044, large fire extinguishers may also be transported unpackaged provided that the requirements of 4.1.3.8.1.1 to 4.1.3.8.1.5 are met, the valves are protected by one of the methods in accordance with 4.1.6.1.8.1 to 4.1.6.1.8.4 and other equipment mounted on the fire extinguisher is protected to prevent accidental activation. For the purpose of this special packing provision, “large fire extinguishers” means fire extinguishers as described in subparagraphs .3 to .5 of special provision 225 of chapter 3.3.

PP100 For UN Nos. 1408 and 2793 flexible, fibreboard or wooden packagings shall be sift-proof and water-resistant or shall be fitted with a sift-proof and water-resistant liner.

 

 P004                                                     PACKING INSTRUCTION                                               P004

This instruction applies to UN Nos. 3473, 3476, 3477, 3478 and 3479.

The following packagings are authorized:

(1)  For fuel cell cartridges, provided that the general provisions of 4.1.1.1, 4.1.1.2, 4.1.1.3, 4.1.1.6 and 4.1.3 are met:

Drums (1A2, 1B2, 1N2, 1H2, 1D, 1G);

Boxes (4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1, 4H2);

Jerricans (3A2, 3B2, 3H2).

Packagings shall conform to the packing group II performance level.

(2)  For fuel cell cartridges packed with equipment: strong outer packagings which meet the general provisions of 4.1.1.1, 4.1.1.2, 4.1.1.6 and 4.1.3.

When fuel cell cartridges are packed with equipment, they shall be packed in inner packagings or placed in the outer packaging with cushioning material or divider(s) so that the fuel cell cartridges are protected against damage that may be caused by the movement or placement of the contents within the outer packaging.

The equipment shall be secured against movement within the outer packaging.

For the purpose of this packing instruction, “equipment” means apparatus requiring the fuel cell cartridges with which it is packed for its operation.

(3)  For fuel cell cartridges contained in equipment: strong outer packagings which meet the general provisions of 4.1.1.1, 4.1.1.2, 4.1.1.6 and 4.1.3.

Large robust equipment (see 4.1.3.8) containing fuel cell cartridges may be transported unpackaged. For fuel cell cartridges contained in equipment, the entire system shall be protected against short circuit and inadvertent operation.

 

P005                                                      PACKING INSTRUCTION                                                               P005

This instruction applies to UN Nos. 3528, 3529 and 3530.

If the engine or machinery is constructed and designed so that the means of containment containing the dangerous goods affords adequate protection, an outer packaging is not required.

Dangerous goods in engines or machinery shall otherwise be packed in outer packagings constructed of suitable material, and of adequate strength and design in relation to the packaging capacity and its intended use, and meeting the applicable requirements of 4.1.1.1, or they shall be fixed in such a way that they will not become loose during normal conditions of transport, e.g. in cradles or crates or other handling devices.

In addition, the manner in which means of containment are contained within the engine or machinery, shall be such that under normal conditions of transport, damage to the means of containment containing the dangerous goods is prevented; and in the event of damage to the means of containment containing liquid dangerous goods, no leakage of the dangerous goods from the engine or machinery is possible (a leakproof liner may be used to satisfy this requirement).

Means of containment containing dangerous goods shall be so installed, secured or cushioned as to prevent their breakage or leakage and so as to control their movement within the engine or machinery during normal conditions of transport. Cushioning material shall not react dangerously with the content of the means of containment. Any leakage of the contents shall not substantially impair the protective properties of the cushioning material.

Additional requirement:

Other dangerous goods (e.g. batteries, fire extinguishers, compressed gas accumulators or safety devices) required for the functioning or safe operation of the engine or machinery shall be securely mounted in the engine or machine.

 

P010                                                      PACKING INSTRUCTION                                               P010

The following packagings are authorized, provided that the general provisions of 4.1.1 and 4.1.3 are met.

Combination packagings

Maximum net mass (see 4.1.3.3)

Inner packagings

Outer packagings

Glass 1 L

Steel 40 L

Drums

 

steel (1A1, 1A2)

400 kg

plastics (1H1, 1H2)

400 kg

plywood (1D)

400 kg

fibre (1G)

400 kg

Boxes

steel (4A)

400 kg

natural wood (4C1, 4C2)

400 kg

plywood (4D)

400 kg

reconstituted wood (4F)

400 kg

fibreboard (4G)

400 kg

expanded plastics (4H1)

60 kg

solid plastics (4H2)

400 kg

Single packagings

Maximum capacity (see 4.1.3.3)

Drums

steel, non-removable head (1A1)

450 L

Jerricans

steel, non-removable head (3A1)

60 L

Composite packagings

plastics receptacle in steel drums (6HA1)

250 L

Steel pressure receptacles

provided that the general provisions of 4.1.3.6 are met.

 

 

P099                                                      PACKING INSTRUCTION                                                               P099

Only packagings which are approved for these goods by the competent authority may be used (see 4.1.3.7). A copy of the competent authority approval shall accompany each consignment or the transport document shall include an indication that the packaging was approved by the competent authority.

P101                                                      PACKING INSTRUCTION                                                               P101

 


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