IMDG Code. Part 2 (2018)

THE INTERNATIONAL MARITIME DANGEROUS GOODS (IMDG) CODE

AMENDMENT 38-16

 (adopted on 13 May 2016 by MSC.406(96))

enter into force on 1 January 2018

 

PART 2

CLASSIFICATION

 

Chapter 2.0. Introduction

Note: For the purposes of this Code, it has been necessary to classify dangerous goods in different classes, to subdivide a number of these classes and to define and describe characteristics and properties of the substances, materials and articles which would fall within each class or division. Moreover, in accordance with the criteria for the selection of marine pollutants for the purposes of Annex III of the International Convention for the Prevention of Pollution from Ships, 1973, as modified by the Protocol of 1978 relating thereto (MARPOL), a number of dangerous substances in the various classes have also been identified as substances harmful to the marine environment (MARINE POLLUTANTS).

2.0.0 Responsibilities

2.0.0.1 The classification shall be made by the shipper/consignor or by the appropriate competent authority where specified in this Code.

2.0.0.2 A consignor who has identified, on the basis of test data, that a substance listed by name in column 2 of the Dangerous Goods List in chapter 3.2 meets classification criteria for a hazard class or division that is not identified in the list, may, with the approval of the competent authority, consign the substance:

       under the most appropriate "generic" or "not otherwise specified" (N.O.S.) entry reflecting all hazards; or

       under the same UN number and name but with additional hazard communication information as appropriate to reflect the additional subsidiary risk(s) (documentation, label, placard) provided that the primary hazard class remains unchanged and that any other transport conditions (e.g. limited quantity, packaging and tank provisions) that would normally apply to substances possessing such a combination of hazards are the same as those applicable to the substance listed.

Note: When a competent authority grants such approvals, it should inform the United Nations Sub-Committee of Experts on the Transport of Dangerous Goods* accordingly and submit a relevant proposal of amendment to the Dangerous Goods List. Should the proposed amendment be rejected, the competent authority should withdraw its approval.

_____________________

*  UNECE United Nations Economic Commission for Europe, Dangerous Goods and Special Cargoes Section, Transport Division. Palais des Nations, Bureau 418, CH-1211 Geneva 10, Switzerland. Tel: +41 22 917 24 56, Fax: +41 22 917 00 39. www.unece.org/trans/ danger/danger.html.

 

2.0.1 Classes, divisions, packing groups

2.0.1.1 Definitions

Substances (including mixtures and solutions) and articles subject to the provisions of this Code are assigned to one of the classes 1–9 according to the hazard or the most predominant of the hazards they present. Some of these classes are subdivided into divisions. These classes or divisions are as listed below:

Class 1: Explosives

Division 1.1: substances and articles which have a mass explosion hazard

Division 1.2: substances and articles which have a projection hazard but not a mass explosion hazard

Division 1.3: substances and articles which have a fire hazard and either a minor blast hazard or a minor projection hazard or both, but not a mass explosion hazard

Division 1.4: substances and articles which present no significant hazard

Division 1.5: very insensitive substances which have a mass explosion hazard

Division 1.6: extremely insensitive articles which do not have a mass explosion hazard

Class 2: Gases

Class 2.1: flammable gases

Class 2.2: non-flammable, non-toxic gases

Class 2.3: toxic gases

Class 3: Flammable liquids

Class 4: Flammable solids; substances liable to spontaneous combustion; substances which, in contact with water, emit flammable gases

Class 4.1: flammable solids, self-reactive substances, solid desensitized explosives and polymerizing substances

Class 4.2: substances liable to spontaneous combustion

Class 4.3: substances which, in contact with water, emit flammable gases

Class 5: Oxidizing substances and organic peroxides

Class 5.1: oxidizing substances

Class 5.2: organic peroxides

Class 6: Toxic and infectious substances

Class 6.1: toxic substances

Class 6.2: infectious substances

Class 7: Radioactive material

Class 8: Corrosive substances

Class 9: Miscellaneous dangerous substances and articles

 

The numerical order of the classes and divisions is not that of the degree of danger.

 

2.0.1.2 Marine pollutants

2.0.1.2.1 Many of the substances assigned to classes 1 to 6.2, 8 and 9 are deemed as being marine pollutants (see chapter 2.10).

2.0.1.2.2 Known marine pollutants are noted in the Dangerous Goods List and are indicated in the Index.

2.0.1.3 For packing purposes, substances other than those of classes 1, 2, 5.2, 6.2 and 7, and other than self-reactive substances of class 4.1, are assigned to three packing groups in accordance with the degree of danger they present:

Packing group I: substances presenting high danger;

Packing group II: substances presenting medium danger; and

Packing group III: substances presenting low danger.

The packing group to which a substance is assigned is indicated in the Dangerous Goods List in chapter 3.2.

Articles are not assigned to packing groups. For packing purposes, any requirement for a specific packaging performance level is set out in the applicable packing instruction.

2.0.1.4 Dangerous goods are determined to present one or more of the dangers represented by classes 1 to 9, marine pollutants and, if applicable, the degree of danger (packing group) on the basis of the provisions in chapters 2.1 to 2.10.

2.0.1.5 Dangerous goods presenting a danger of a single class or division are assigned to that class or division and the packing group, if applicable, determined. When an article or substance is specifically listed by name in the Dangerous Goods List in chapter 3.2, its class or division, its subsidiary risk(s) and, when applicable, its packing group are taken from this list.

2.0.1.6 Dangerous goods meeting the defining criteria of more than one hazard class or division and which are not listed by name in the Dangerous Goods List are assigned to a class or division and subsidiary risk(s) on the basis of the precedence of hazard provisions prescribed in 2.0.3.

2.0.2 UN numbers and proper shipping names

2.0.2.1 Dangerous goods are assigned to UN numbers and proper shipping names according to their hazard classification and their composition.

2.0.2.2 Dangerous goods commonly transported are listed in the Dangerous Goods List in chapter 3.2. Where an article or substance is specifically listed by name, it shall be identified in transport by the proper shipping name in the Dangerous Goods List. Such substances may contain technical impurities (for example those deriving from the production process) or additives for stability or other purposes that do not affect their classification. However, a substance listed by name containing technical impurities or additives for stability or other purposes affecting its classification shall be considered a mixture or solution (see 2.0.2.5). For dangerous goods not specifically listed by name, “generic” or “not otherwise specified” entries are provided (see 2.0.2.7) to identify the article or substance in transport. The substances listed by name in column (2) of the Dangerous Goods List of chapter 3.2 shall be transported according to their classification in the list or under the conditions specified in 2.0.0.2.

Each entry in the Dangerous Goods List is assigned a UN number. This list also contains relevant information for each entry, such as hazard class, subsidiary risk(s) (if any), packing group (where assigned), packing and tank transport provisions, EmS, segregation and stowage, properties and observations, etc.

Entries in the Dangerous Goods List are of the following four types:

.1       single entries for well-defined substances or articles:

e.g. UN 1090 acetone

UN 1194 ethyl nitrite solution

.2       generic entries for well-defined groups of substances or articles:

e.g. UN 1133 adhesives

UN 1266 perfumery product

UN 2757 carbamate pesticide, solid, toxic

UN 3101 organic peroxide type B, liquid

.3       specific N.O.S. entries covering a group of substances or articles of a particular chemical or technical nature:

e.g. UN 1477 nitrates, inorganic, N.O.S.

UN 1987 alcohols, N.O.S.

.4       general N.O.S. entries covering a group of substances or articles meeting the criteria of one or more classes:

e.g. UN 1325 flammable solid, organic, N.O.S.

UN 1993 flammable liquid, N.O.S.

2.0.2.3 All self-reactive substances of class 4.1 are assigned to one of 20 generic entries in accordance with the classification principles described in 2.4.2.3.3.

2.0.2.4 All organic peroxides of class 5.2 are assigned to one of 20 generic entries in accordance with the classification principles described in 2.5.3.3.

2.0.2.5 A mixture or solution meeting the classification criteria of this Code composed of a single predominant substance identified by name in the Dangerous Goods List and one or more substances not subject to the provisions of this Code and/or traces of one or more substances identified by name in the Dangerous Goods List, shall be assigned the UN number and proper shipping name of the predominant substance named in the Dangerous Goods List unless:

.1       the mixture or solution is identified by name in the Dangerous Goods List;

.2       the name and description of the substance named in the Dangerous Goods List specifically indicate that they apply only to the pure substance;

.3       the hazard class or division, subsidiary risk(s), packing group, or physical state of the mixture or solution is different from that of the substance named in the Dangerous Goods List; or

.4       the hazard characteristics and properties of the mixture or solution necessitate emergency response measures that are different from those required for the substance identified by name in the Dangerous Goods List.

In those other cases, except the one described in .1, the mixture or solution shall be treated as a dangerous substance not specifically listed by name in the Dangerous Goods List.

2.0.2.6 When the class, physical state or packing group has changed in comparison with the pure substance, the solution or mixture shall be shipped in accordance with the provisions for the changed hazard under an appropriate N.O.S. entry.

2.0.2.7 Substances or articles which are not specifically listed by name in the Dangerous Goods List shall be classified under a “generic” or “not otherwise specified” (N.O.S.) proper shipping name. The substance or article shall be classified according to the class definitions and test criteria in this part, and the article or substance classified under the generic or “N.O.S.” proper shipping name in the Dangerous Goods List which most appropriately describes the article or substance. This means that a substance is only to be assigned to an entry of type .3, as defined in 2.0.2.2, if it cannot be assigned to an entry of type .2, and to an entry of type .4 if it cannot be assigned to an entry of type .2 or .3.*

_________________________

*  See also the generic or N.O.S. proper shipping name in appendix A.

 

2.0.2.8 When considering a solution or mixture in accordance with 2.0.2.5, due account shall be given to whether the dangerous constituent comprising the solution or mixture has been identified as a marine pollutant. If this is the case, the provisions of chapter 2.10 are also applicable.

2.0.2.9 A mixture or solution, containing one or more substances identified by name in this Code or classified under an N.O.S. or generic entry and one or more substances not subject to the provisions of this Code, is not subject to the provisions of this Code if the hazard characteristics of the mixture or solution are such that they do not meet the criteria (including human experience criteria) for any class.

2.0.2.10 A mixture or solution meeting the classification criteria of this Code that is not identified by name in the Dangerous Goods List and that is composed of two or more dangerous goods shall be assigned to an entry that has the proper shipping name, description, hazard class or division, subsidiary risk(s) and packing group that most precisely describe the mixture or solution.

2.0.3 Classification of substances, mixtures and solutions with multiple hazards (precedence of hazard characteristics)

2.0.3.1 The table of precedence of hazard characteristics in 2.0.3.6 shall be used to determine the class of a substance, mixture or solution having more than one hazard when it is not specifically listed by name in this Code. For substances, mixtures or solutions having multiple hazards which are not specifically listed by name, the most stringent packing group of those assigned to the respective hazards of the goods takes precedence over other packing groups, irrespective of the precedence of hazard table in 2.0.3.6.

2.0.3.2 The precedence of hazard table indicates which of the hazards shall be regarded as the primary hazard. The class which appears at the intersection of the horizontal line and the vertical column is the primary hazard and the remaining class is the subsidiary hazard. The packing groups for each of the hazards associated with the substance, mixture or solution shall be determined by reference to the appropriate criteria. The most stringent of the groups so indicated shall then become the packing group of the substance, mixture or solution.

2.0.3.3 The proper shipping name (see 3.1.2) of a substance, mixture or solution when classified in accordance with 2.0.3.1 and 2.0.3.2 shall be the most appropriate N.O.S. (“not otherwise specified”) entry in this Code for the class shown as the primary hazard.

2.0.3.4 The precedence of hazard characteristics of the following substances, materials and articles have not been dealt with in the precedence of hazard table, as these primary hazards always take precedence:

.1       substances and articles of class 1;

.2       gases of class 2;

.3       liquid desensitized explosives of class 3;

.4       self-reactive substances and solid desensitized explosives of class 4.1;

.5       pyrophoric substances of class 4.2;

.6       substances of class 5.2;

.7       substances of class 6.1 with a packing group I vapour inhalation toxicity;

.8       substances of class 6.2; and

.9       materials of class 7.

2.0.3.5 Apart from excepted radioactive material (where the other hazardous properties take precedence), radioactive material having other hazardous properties shall always be classified in class 7, with the greatest of the additional hazards being identified. For radioactive material in excepted packages, except for UN 3507, URANIUM HEXAFLUORIDE, RADIOACTIVE MATERIAL, EXCEPTED PACKAGE, special provision 290 of chapter 3.3 applies.

 2.0.3.6 Precedence of hazards

Class and Packing Group

4.2

4.3

5.1

I

5.1

II

5.1

III

6.1, I

Dermal

6.1, I

Oral

6.1

II

6.1

III

8, I

Liquid

8, I

Solid

8, II

Liquid

8, II

Solid

8, III

Liquid

8, III

Solid

3

I*

 

4.3

 

 

 

3

3

3

3

3

3

3

3

II*

 

4.3

 

 

 

3

3

3

3

8

3

3

3

III*

 

4.3

 

 

 

6.1

6.1

6.1

3

8

8

3

4.1

II*

4.2

4.3

5.1

4.1

4.1

6.1

6.1

4.1

4.1

8

4.1

4.1

4.1

III*

4.2

4.3

5.1

4.1

4.1

6.1

6.1

6.1

4.1

8

8

4.1

4.2

II

 

4.3

5.1

4.2

4.2

6.1

6.1

4.2

4.2

8

8

4.2

4.2

4.2

4.2

4.2

III

 

4.3

5.1

5.1

4.2

6.1

6.1

6.1

4.2

8

8

8

8

4.2

4.2

4.3

I

 

 

5.1

4.3

4.3

6.1

4.3

4.3

4.3

4.3

4.3

4.3

4.3

4.3

4.3

4.3

II

 

 

5.1

4.3

4.3

6.1

4.3

4.3

4.3

8

8

4.3

4.3

4.3

4.3

4.3

III

 

 

5.1

5.1

4.3

6.1

6.1

6.1

4.3

8

8

8

8

4.3

4.3

5.1

I

 

 

 

 

 

5.1

5.1

5.1

5.1

5.1

5.1

5.1

5.1

5.1

5.1

5.1

II

 

 

 

 

 

6.1

5.1

5.1

5.1

8

8

5.1

5.1

5.1

5.1

5.1

III

 

 

 

 

 

6.1

6.1

6.1

5.1

8

8

8

8

5.1

5.1

6.1

I, Dermal

 

 

 

 

 

 

 

 

 

8

6.1

6.1

6.1

6.1

6.1

6.1

I, Oral

 

 

 

 

 

 

 

 

 

8

6.1

6.1

6.1

6.1

6.1

6.1

II, Inhalation

 

 

 

 

 

 

 

 

 

8

6.1

6.1

6.1

6.1

6.1

6.1

II, Dermal

 

 

 

 

 

 

 

 

 

8

6.1

8

6.1

6.1

6.1

6.1

II, Oral

 

 

 

 

 

 

 

 

 

8

8

8

6.1

6.1

6.1

6.1

III

 

 

 

 

 

 

 

 

 

8

8

8

8

8

8

 

*      Substances of class 4.1 other than self-reactive substances and solid desensitized explosives and substances of class 3 other than liquid desensitized explosives.

        6.1 for pesticides.

  Denotes an impossible combination.

For hazards not shown in this table, see 2.0.3.4 and 2.0.3.5.

2.0.4 Transport of samples

2.0.4.1 When the hazard class of a substance is uncertain and it is being transported for further testing, a tentative hazard class, proper shipping name and identification number shall be assigned on the basis of the consignor’s knowledge of the substances and application of:

.1       the classification criteria of this Code; and

.2       the precedence of hazards given in 2.0.3.

The most severe packing group possible for the proper shipping name chosen shall be used.

Where this provision is used, the proper shipping name shall be supplemented with the word “SAMPLE” (such as FLAMMABLE LIQUID, N.O.S., SAMPLE). In certain instances, where a specific proper shipping name is provided for a sample of a substance considered to meet certain classification criteria (such as UN 3167, GAS SAMPLE, NON-PRESSURIZED, FLAMMABLE), that proper shipping name shall be used. When an N.O.S. entry is used to transport the sample, the proper shipping name need not be supplemented with the technical name as required by special provision 274.

2.0.4.2 Samples of the substance shall be transported in accordance with the provisions applicable to the tentative assigned proper shipping name provided:

.1       the substance is not considered to be a substance prohibited for transport by 1.1.3;

.2       the substance is not considered to meet the criteria for class 1 or considered to be an infectious substance or a radioactive material;

.3       the substance is in compliance with 2.4.2.3.2.4.2 or 2.5.3.2.5.1 if it is a self-reactive substance or an organic peroxide, respectively;

.4       the sample is transported in a combination packaging with a net mass per package not exceeding 2.5 kg; and

.5       the sample is not packed together with other goods.

2.0.5 Transport of wastes

2.0.5.1 Preamble

Wastes, which are dangerous goods, shall be transported in accordance with the relevant international recommendations and conventions and, in particular, where it concerns transport by sea, with the provisions of this Code.

2.0.5.2 Applicability

2.0.5.2.1 The provisions of this chapter are applicable to the transport of wastes by ships and shall be considered in conjunction with all other provisions of this Code.

2.0.5.2.2 Substances, solutions, mixtures or articles containing or contaminated with radioactive material are subject to the applicable provisions for radioactive material in class 7, and are not to be considered as wastes for the purposes of this chapter.

2.0.5.3 Transboundary movements under the Basel Convention*

________________________

*  Basel Convention on the Control of Transboundary Movements of Hazardous Wastes and their Disposal (1989).

 

2.0.5.3.1 Transboundary movement of wastes is permitted to commence only when:

.1       notification has been sent by the competent authority of the country of origin, or by the generator or exporter through the channel of the competent authority of the country of origin, to the country of final destination; and

.2       the competent authority of the country of origin, having received the written consent of the country of final destination stating that the wastes will be safely incinerated or treated by other methods of disposal, has given authorization to the movement.

2.0.5.3.2 In addition to the transport document required in chapter 5.4, all transboundary movements of wastes shall be accompanied by a waste movement document from the point at which a transboundary movement commences to the point of disposal. This document shall be available at all times to the competent authorities and to all persons involved in the management of waste transport operations.

2.0.5.3.3 The transport of solid wastes in bulk in cargo transport units and road vehicles is only permitted with the approval of the competent authority of the country of origin.

2.0.5.3.4 In the event that packages and cargo transport units containing wastes are suffering from leakage or spillage, the competent authorities of the countries of origin and destination shall be immediately informed and advice on the action to be taken obtained from them.

2.0.5.4 Classification of wastes

2.0.5.4.1 A waste containing only one constituent which is a dangerous substance subject to the provisions of this Code shall be regarded as being that particular substance. If the concentration of the constituent is such that the waste continues to present a hazard inherent in the constituent itself, it shall be classified according to the criteria of the applicable classes.

2.0.5.4.2 A waste containing two or more constituents which are dangerous substances subject to the provisions of this Code shall be classified under the applicable class in accordance with their dangerous characteristics and properties as described in 2.0.5.4.3 and 2.0.5.4.4.

2.0.5.4.3 The classification according to the dangerous characteristics and properties shall be carried out as follows:

.1       determination of the physical and chemical characteristics and physiological properties by measurement or calculation followed by classification according to the criteria of the applicable class(es); or

.2       if the determination is not practicable, the waste shall be classified according to the constituent presenting the predominant hazard.

2.0.5.4.4 In determining the predominant hazard, the following criteria shall be taken into account:

.1       if one or more constituents fall within a certain class and the waste presents a hazard inherent in these constituents, the waste shall be included in that class; or

.2       if there are constituents falling under two or more classes, the classification of the waste shall take into account the order of precedence applicable to dangerous substances with multiple hazards set out in 2.0.3.

2.0.5.4.5 Wastes harmful to the marine environment only shall be transported under the class 9 entries for ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., UN 3082, or ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., UN 3077, with the addition of the word “WASTE”. However, this is not applicable to substances which are covered by individual entries in this Code.

2.0.5.4.6 Wastes not otherwise subject to the provisions of this Code but covered under the Basel Convention may be transported under the class 9 entries for ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., UN 3082 or ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., UN 3077 with the addition of the word WASTE.

 

Chapter 2.1. Class 1 – Explosives

2.1.0 Introductory notes (these notes are not mandatory)

Note 1:      Class 1 is a restricted class, that is, only those explosive substances and articles that are listed in the Dangerous Goods List in chapter 3.2 may be accepted for transport. However, the competent authorities retain the right by mutual agreement to approve transport of explosive substances and articles for special purposes under special conditions. Therefore entries have been included in the Dangerous Goods List for “Substances, explosive, not otherwise specified” and “Articles, explosive, not otherwise specified”. It is intended that these entries should only be used when no other method of operation is possible.

Note 2:      General entries such as “Explosive, blasting, type A” are used to allow for the transport of new substances. In preparing these provisions, military ammunition and explosives have been taken into consideration to the extent that they are likely to be transported by commercial carriers.

Note 3:      A number of substances and articles in class 1 are described in appendix B. These descriptions are given because a term may not be well-known or may be at variance with its usage for regulatory purposes.

Note 4:      Class 1 is unique in that the type of packaging frequently has a decisive effect on the hazard and therefore on the assignment to a particular division. The correct division is determined by use of the procedures provided in this chapter.

2.1.1 Definitions and general provisions

2.1.1.1 Class 1 comprises:

.1       explosive substances (a substance which is not itself an explosive but which can form an explosive atmosphere of gas, vapour or dust is not included in class 1), except those which are too dangerous to transport or those where the predominant hazard is one appropriate to another class;

.2       explosive articles, except devices containing explosive substances in such quantity or of such a character that their inadvertent or accidental ignition or initiation during transport shall not cause any effect external to the device either by projection, fire, smoke, heat or loud noise (see 2.1.3.4); and

.3       substances and articles not mentioned under .1 and .2 which are manufactured with a view to producing a practical, explosive or pyrotechnic effect.

2.1.1.2 Transport of explosive substances which are unduly sensitive, or so reactive as to be subject to spontaneous reaction, is prohibited.

2.1.1.3 Definitions

For the purposes of this Code, the following definitions apply:

.1       Explosive substance means a solid or liquid substance (or a mixture of substances) which is in itself capable by chemical reaction of producing gas at such a temperature and pressure and at such a speed as to cause damage to the surroundings. Pyrotechnic substances are included even when they do not evolve gases.

.2       Pyrotechnic substance means a substance or a mixture of substances designed to produce an effect by heat, light, sound, gas or smoke or a combination of these as the result of non-detonative self-sustaining exothermic chemical reactions.

.3       Explosive article means an article containing one or more explosive substances.

.4       Mass explosion means one which affects almost the entire load virtually instantaneously.

.5       Phlegmatized means that a substance (or “phlegmatizer”) has been added to an explosive to enhance its safety in handling and transport. The phlegmatizer renders the explosive insensitive, or less sensitive, to the following actions: heat, shock, impact, percussion or friction. Typical phlegmatizing agents include, but are not limited to: wax, paper, water, polymers (such as chlorofluoropolymers), alcohol and oils (such as petroleum jelly and paraffin).

2.1.1.4 Hazard divisions

The six hazard divisions of class 1 are:

Division 1.1          Substances and articles which have a mass explosion hazard

Division 1.2          Substances and articles which have a projection hazard but not a mass explosion hazard

Division 1.3          Substances and articles which have a fire hazard and either a minor blast hazard or a minor projection hazard or both, but not a mass explosion hazard

This division comprises substances and articles:

.1     which give rise to considerable radiant heat; or

.2     which burn one after another, producing minor blast or projection effects or both.

Division 1.4          Substances and articles which present no significant hazard

This division comprises substances and articles which present only a small hazard in the event of ignition or initiation during transport. The effects are largely confined to the package and no projection of fragments of appreciable size or range is to be expected. An external fire must not cause virtually instantaneous explosion of almost the entire contents of the package.

Note: Substances and articles in this division are in compatibility group S if they are so packaged or designed that any hazardous effects arising from the accidental functioning are confined within the package unless the package has been degraded by fire, in which case all blast or projection effects are limited to the extent that they do not significantly hinder fire fighting or other emergency response efforts in the immediate vicinity of the package.

Division 1.5          Very insensitive substances which have a mass explosion hazard

This division comprises substances which have a mass explosion hazard but are so insensitive that there is very little probability of initiation or of transition from burning to detonation under normal conditions of transport.

Note: The probability of transition from burning to detonation is greater when large quantities are transported in a ship. As a consequence, the stowage provisions for explosive substances in division 1.1 and for those in division 1.5 are identical.

Division 1.6          Extremely insensitive articles which do not have a mass explosion hazard

This division comprises articles which predominantly contain extremely insensitive substances and which demonstrate a negligible probability of accidental initiation or propagation.

Note: The risk from articles of division 1.6 is limited to the explosion of a single article.

2.1.1.5 Any substance or article having or suspected of having explosive characteristics shall first be considered for classification in class 1 in accordance with the procedures in 2.1.3. Goods are not classified in class 1 when:

.1       unless specially authorized, the transport of an explosive substance is prohibited because sensitivity of the substance is excessive;

.2       the substance or article comes within the scope of those explosive substances and articles which are specifically excluded from class 1 by the definition of this class; or

.3       the substance or article has no explosive properties.

2.1.2 Compatibility groups and classification codes

2.1.2.1 Goods of class 1 are considered to be “compatible” if they can be safely stowed or transported together without significantly increasing either the probability of an accident or, for a given quantity, the magnitude of the effects of such an accident. By this criterion, goods listed in this class have been divided into a number of compatibility groups, each denoted by a letter from A to L (excluding I), N and S. These are described in 2.1.2.2 and 2.1.2.3.

2.1.2.2 Compatibility groups and classification codes

Description of substance or articles to be classified

Compatibility group

Classification code

Primary explosive substance

A

1.1A

Article containing a primary explosive substance and not containing two or more effective protective features. Some articles, such as detonators for blasting, detonator assemblies for blasting and primers, cap-type, are included even though they do not contain primary explosives

B

1.1B

1.2B

1.4B

Propellant explosive substance or other deflagrating explosive substance or article containing such explosive substance

C

1.1C

1.2C

1.3C

1.4C

Secondary detonating explosive substance or black powder or article containing a secondary detonating explosive substance, in each case without means of initiation and without a propelling charge, or article containing a primary explosive substance and containing two or more effective protective features

D

1.1D

1.2D

1.4D

1.5D

Article containing a secondary detonating explosive substance, without means of initiation, with a propelling charge (other than one containing a flammable liquid or gel or hypergolic liquids)

E

1.1E

1.2E

1.4E

Article containing a secondary detonating explosive substance with its own means of initiation, with a propelling charge (other than one containing a flammable liquid or gel or hypergolic liquids) or without a propelling charge

F

1.1F

1.2F

1.3F

1.4F

Pyrotechnic substance, or article containing a pyrotechnic substance, or article containing both an explosive substance and an illuminating, incendiary, tear- or smoke-producing substance (other than a water-activated article or one containing white phosphorus, phosphides, a pyrophoric substance, a flammable liquid or gel, or hypergolic liquids)

G

1.1G

1.2G

1.3G

1.4G

Article containing both an explosive substance and white phosphorus

H

1.2H

1.3H

Article containing both an explosive substance and a flammable liquid or gel

J

1.1J

1.2J

1.3J

Article containing both an explosive substance and a toxic chemical agent

K

1.2K

1.3K

Explosive substance or article containing an explosive substance and presenting a special risk (such as due to water-activation or presence of hypergolic liquids, phosphides or a pyrophoric substance) and needing isolation of each type (see 7.2.7.1.4, note 2)

L

1.1L

1.2L

1.3L

Articles predominantly containing extremely insensitive substances

N

1.6N

Substance or article so packaged or designed that any hazardous effects arising from accidental functioning are confined within the package unless the package has been degraded by fire, in which case all blast or projection effects are limited to the extent that they do not significantly hinder or prohibit fire fighting or other emergency response efforts in the immediate vicinity of the package

S

1.4S

 

Note 1: Articles of compatibility groups D and E may be fitted or packed together with their own means of initiation provided that such means have at least two effective protective features designed to prevent an explosion in the event of accidental functioning of the means of initiation. Such articles and packages shall be assigned to compatibility groups D or E.

 

Note 2: Articles of compatibility groups D and E may be packed together with their own means of initiation, which do not have two effective protective features when, in the opinion of the competent authority of the country of origin, the accidental functioning of the means of initiation does not cause the explosion of an article under normal conditions of transport. Such packages shall be assigned to compatibility groups D or E.

 

2.1.2.3 Scheme of classification of explosives, combination of hazard division with compatibility group

Hazard division

Compatibility group

∑ A–S

A

B

C

D

E

F

G

H

J

K

L

N

S

 

1.1

1.1A

1.1B

1.1C

1.1D

1.1E

1.1F

1.1G

 

1.1J

 

1.1L

 

 

9

1.2

 

1.2B

1.2C

1.2D

1.2E

1.2F

1.2G

1.2H

1.2J

1.2K

1.2L

 

 

10

1.3

 

 

1.3C

 

 

1.3F

1.3G

1.3H

1.3J

1.3K

1.3L

 

 

7

1.4

 

1.4B

1.4C

1.4D

1.4E

1.4F

1.4G

 

 

 

 

 

1.4S

7

1.5

 

 

 

1.5D

 

 

 

 

 

 

 

 

 

1

1.6

 

 

 

 

 

 

 

 

 

 

 

1.6N

 

1

1.1–1.6

1

3

4

4

3

4

4

2

3

2

3

1

1

35

 

2.1.2.4 The definitions of compatibility groups in 2.1.2.2 are intended to be mutually exclusive, except for a substance or article which qualifies for compatibility group S. Since the criterion of compatibility group S is an empirical one, assignment to this group is necessarily linked to the tests for assignment to division 1.4.

2.1.3 Classification procedure

2.1.3.1 Any substance or article having or suspected of having explosive characteristics shall be considered for classification in class 1. Substances and articles classified in class 1 shall be assigned to the appropriate division and compatibility group. Goods of class 1 shall be classified in accordance with the latest version of the Manual of Tests and Criteria.

2.1.3.2 Prior to transport, the classification of all explosive substances and articles, together with the compatibility group assignment and the proper shipping name under which the substance or article is to be transported, shall have been approved by the competent authority of the country of manufacture. A new approval would be required for:

.1       a new explosive substance; or

.2       a new combination or mixture of explosive substances which is significantly different from other combinations or mixtures previously manufactured and approved; or

.3       a new design of an explosive article, an article containing a new explosive substance, or an article containing a new combination or mixture of explosive substances; or

.4       an explosive substance or article with a new design or type of packaging, including a new type of inner packaging.

2.1.3.3 Assessment of the hazard division is usually made on the basis of test results. A substance or article shall be assigned to the hazard division which corresponds to the results of the tests to which the substance or article, as offered for transport, has been subjected. Other test results, and data assembled from accidents which have occurred, may also be taken into account.

2.1.3.4 Exclusion from class 1

2.1.3.4.1 The competent authority may exclude an article or substance from class 1 by virtue of test results and the class 1 definition.

2.1.3.4.2 An article may be excluded from class 1 by the competent authority when three unpackaged articles, each individually activated by its own means of initiation or ignition or external means to function in the designed mode, meet the following test criteria:

.1       no external surface shall have a temperature of more than 65°C. A momentary spike in temperature up to 200°C is acceptable;

.2       no rupture or fragmentation of the external casing or movement of the article or detached parts thereof of more than one metre in any direction;

Note: Where the integrity of the article may be affected in the event of an external fire these criteria shall be examined by a fire test, such as described in ISO 12097-3.

.3       no audible report exceeding 135 dB(C) peak at a distance of one metre;

.4       no flash or flame capable of igniting a material such as a sheet of 80 ± 10 g/m² paper in contact with the article; and

.5       no production of smoke, fumes or dust in such quantities that the visibility in a one cubic metre chamber equipped with appropriately sized blow out panels is reduced more than 50% as measured by a calibrated light (lux) meter or radiometer located one metre from a constant light source located at the midpoint on opposite walls. The general guidance on Optical Density Testing in ISO 5659-1 and the general guidance on the Photometric System described in Section 7.5 in ISO 5659-2 may be used or similar optical density measurement methods designed to accomplish the same purpose may also be employed. A suitable hood cover surrounding the back and sides of the light meter shall be used to minimize effects of scattered or leaking light not emitted directly from the source.

Note 1: If during the tests addressing criteria .1, .2, .3 and .4 no or very little smoke is observed the test described in .5 may be waived.

Note 2: The competent authority may require testing in packaged form if it is determined that, as packaged for transport, the article may pose a greater risk.

2.1.3.5 Assignment of fireworks to hazard divisions

2.1.3.5.1 Fireworks shall normally be assigned to hazard divisions 1.1, 1.2, 1.3, and 1.4 on the basis of test data derived from Test Series 6 of the Manual of Tests and Criteria. However:

.1       waterfalls giving a positive result when tested in the HSL Flash composition test in appendix 7 of the Manual of Tests and Criteria shall be classified as 1.1G regardless of the results of Test Series 6;

.2       since the range of fireworks is very extensive and the availability of test facilities may be limited, assignment to hazard divisions may also be made in accordance with the procedure in 2.1.3.5.2.

2.1.3.5.2 Assignment of fireworks to UN Nos. 0333, 0334, 0335 or 0336 may be made on the basis of analogy, without the need for Test Series 6 testing, in accordance with the default fireworks classification table in 2.1.3.5.5. Such assignment shall be made with the agreement of the competent authority. Items not specified in the table shall be classified on the basis of test data derived from Test Series 6 of the Manual of Tests and Criteria.

Note: The addition of other types of fireworks to column 1 of the table in 2.1.3.5.5 shall only be made on the basis of full test data submitted to the UN Sub-Committee of Experts on the Transport of Dangerous Goods for consideration.

2.1.3.5.3 Where fireworks of more than one hazard division are packed in the same package they shall be classified on the basis of the highest hazard division unless test data derived from Test Series 6 of the Manual of Tests and Criteria indicate otherwise.

2.1.3.5.4 The classification shown in the table in 2.1.3.5.5 applies only for articles packed in fibreboard boxes (4G).

2.1.3.5.5 Default fireworks classification table*

________________________

*    This table contains a list of firework classifications that may be used in the absence of Test Series 6, of the Manual of Tests and Criteria, data (see 2.1.3.5.2).

 

Note 1: References to percentages in the table, unless otherwise stated, are to the mass of all pyrotechnic substances (e.g. rocket motors, lifting charge, bursting charge and effect charge).

Note 2: “Flash composition” in this table refers to pyrotechnic substances in powder form or as pyrotechnic units as presented in the fireworks that are used to

produce an aural effect or used as a bursting charge, or propellant charge unless the time taken for the pressure rise is demonstrated to be more than 6 ms for 0.5 g of pyrotechnic substance in the HSL Flash Composition Test in appendix 7 of the Manual of Tests and Criteria.

Note 3: Dimensions in mm refers to:

– for spherical and peanut shells, the diameter of the sphere of the shell;

– for cylinder shells, the length of the shell;

– for a shell in mortar, Roman candle, shot tube firework or mine, the inside diameter of the tube comprising or containing the firework;

– for a bag mine or cylinder mine, the inside diameter of the mortar intended to contain the mine.

 

Type

Includes: / Synonym:

Definition

Specification

Classification

Shell, spherical or cylindrical

Spherical display shell: aerial shell, colour shell, dye shell, multi-break shell, multi-effect shell, nautical shell, parachute shell, smoke shell, star shell; report shell: maroon, salute, sound shell, thunderclap, aerial shell kit

Device with or without propellant charge, with delay fuse and bursting charge, pyrotechnic unit(s) or loose pyrotechnic substance and designed to be projected from a mortar

All report shells

1.1G

Colour shell:    180 mm

1.1G

Colour shell:  <  180 mm with  >  25% flash composition, as loose powder and/or report effects

1.1G

Colour shell:  <  180 mm with    25% flash composition, as loose powder and/or report effects

1.3G

Colour shell:    50 mm, or    60 g pyrotechnic substance, with    2% flash composition as loose powder and/or report effects

1.4G

Peanut shell

Device with two or more spherical aerial shells in a common wrapper propelled by the same propellant charge with separate external delay fuses

The most hazardous spherical aerial shell determines the classification

 

Preloaded mortar, shell in mortar

Assembly comprising a spherical or cylindrical shell inside a mortar from which the shell is designed to be projected

All report shells

 

Colour shell:    180 mm

1.1G

Colour shell:  >  25% flash composition as loose powder and/or report effects

1.1G

Colour shell:  >  50 mm and  <  180 mm

1.2G

Colour shell:    50 mm, or  <  60 g pyrotechnic substance, with    25% flash composition as loose powder and/or report effects

1.3G

Shell of shells (spherical)

(Reference to percentages for shell of shells are to the gross mass of the fireworks article)

Device without propellant charge, with delay fuse and bursting charge, containing report shells and inert materials and designed to be projected from a mortar

> 120 mm

1.1G

Device without propellant charge, with delay fuse and bursting charge, containing report shells    25 g flash composition per report unit, with    33% flash composition and    60% inert materials and designed to be projected from a mortar

  120 mm

1.3G

Device without propellant charge, with delay fuse and bursting charge, containing colour shells and/or pyrotechnic units and designed to be projected from a mortar

> 300 mm

1.1G

Device without propellant charge, with delay fuse and bursting charge, containing colour shells    70 mm and/or pyrotechnic units, with    25% flash composition and    60% pyrotechnic substance and designed to be projected from a mortar

> 200 mm and    300 mm

1.3G

Device with propellant charge, with delay fuse and bursting charge, containing colour shells    70 mm and/or pyrotechnic units, with    25% flash composition and    60% pyrotechnic substance and designed to be projected from a mortar

  200 mm

1.3G

Battery/ combination

Barrage, bombardos, cakes, finale box, flowerbed, hybrid, multiple tubes, shell cakes, banger batteries, flash banger batteries

Assembly including several elements either containing the same type or several types each corresponding to one of the types of fireworks listed in this table, with one or two points of ignition

The most hazardous firework type determines the classification

 

Roman candle

Exhibition candle, candle, bombettes

Tube containing a series of pyrotechnic units consisting of alternate pyrotechnic substance, propellant charge, and transmitting fuse

  50 mm inner diameter, containing flash composition, or  <  50 mm with  >  25% flash composition

1.1G

  50 mm inner diameter, containing no flash composition

1.2G

<  50 mm inner diameter and    25% flash composition

1.3G

  30 mm inner diameter, each pyrotechnic unit    25 g and    5% flash composition

1.4G

Shot tube

Single shot Roman candle, small preloaded mortar

Tube containing a pyrotechnic unit consisting of pyrotechnic substance, propellant charge with or without transmitting fuse

  30 mm inner diameter and pyrotechnic unit  >  25 g, or  >  5% and    25% flash composition

1.3G

  30 mm inner diameter, pyrotechnic unit

  25 g and    5% flash composition

1.4G

Rocket

Avalanche rocket, signal rocket, whistling rocket, bottle rocket, sky rocket, missile type rocket, table rocket

Tube containing pyrotechnic substance and/or pyrotechnic units, equipped with stick(s) or other means for stabilization of flight, and designed to be propelled into the air

Flash composition effects only

1.1G

Flash composition  >  25% of the pyrotechnic substance

1.1G

> 20 g pyrotechnic substance and flash composition    25 %

1.3G

  20 g pyrotechnic substance, black powder bursting charge and    0.13 g flash composition per report and    1 g in total

1.4G

Mine

Pot-a-feu, ground mine, bag mine, cylinder mine

Tube containing propellant charge and pyrotechnic units and designed to be placed on the ground or to be fixed in the ground.

The principal effect is ejection of all the pyrotechnic units in a single burst producing a widely dispersed visual and/or aural effect in the air or:

Cloth or paper bag or cloth or paper cylinder containing propellant charge and pyrotechnic units, designed to be placed in a mortar and to function as a mine

> 25% flash composition, as loose powder and/or report effects

1.1G

  180 mm and    25% flash composition, as loose powder and/or report effects

1.1G

<  180 mm and    25% flash composition, as loose powder and/or report effects

1.3G

  150 g pyrotechnic substance, containing

  5% flash composition as loose powder and/or report effects.

Each pyrotechnic unit    25 g, each report effect  <  2 g; each whistle, if any,    3 g

1.4G

Fountain

Volcanos, gerbs, lances, Bengal fire, flitter sparkle, cylindrical fountains, cone fountains, illuminating torch

Non-metallic case containing pressed or consolidated pyrotechnic substance producing sparks and flame

Note: Fountains intended to produce a vertical cascade or curtain of sparks are considered to be waterfalls (see row below).

  1 kg pyrotechnic substance

1.3G

<  1 kg pyrotechnic substance

1.4G

Waterfall

Cascades, showers

Pyrotechnic fountain intended to produce a vertical cascade or curtain of sparks

Containing a pyrotechnic substance which gives a positive result when tested in the HSL Flash composition test in appendix 7 of the Manual of Tests and Criteria regardless of the results of Test Series 6 (see 2.1.3.5.1.1)

1.1G

Containing a pyrotechnic substance which gives a negative result when tested in the HSL Flash composition test in appendix 7 of the Manual of Tests and Criteria

1.3G

Sparkler

Handheld sparklers, non-handheld sparklers, wire sparklers

Rigid wire partially coated (along one end) with slow-burning pyrotechnic substance with or without an ignition tip

Perchlorate based sparklers:  >  5 g per item or  >  10 items per pack

1.4G

Perchlorate based sparklers:    5 g per item and    10 items per pack

Nitrate based sparklers:    30 g per item

1.3G

Bengal stick

Dipped stick

Non-metallic stick partially coated (along one end) with slow-burning pyrotechnic substance and designed to be held in the hand

Perchlorate based items:  >  5 g per item or  >  10 items per pack

1.3G

Perchlorate based items:  ≤ 5 g per item and    10 items per pack; nitrate based items:    30 g per item

1.4G

Low hazard fireworks and novelties

Table bombs, throwdowns, crackling granules, smokes, fog, snakes, glow worm, serpents, snaps, party poppers

Device designed to produce very limited visible and/or audible effect which contains small amounts of pyrotechnic and/or explosive substance

Throwdowns and snaps may contain up to 1.6 mg of silver fulminate; snaps and party poppers may contain up to 16 mg of potassium chlorate/red phosphorus mixture; other articles may contain up to 5 g of pyrotechnic substance, but no flash composition

1.4G

Spinner

Aerial spinner, helicopter, chaser, ground spinner

Non-metallic tube or tubes containing gas- or spark-producing pyrotechnic substance, with or without noise-producing substance, with or without aerofoils attached

Pyrotechnic substance per item  >  20 g, containing    3% flash composition as report effects, or whistle composition  ≤ 5 g

1.3G

Pyrotechnic substance per item    20 g, containing    3% flash composition as report effects, or whistle composition  ≤ 5 g

1.4G

Wheels

Catherine wheels, Saxon

Assembly including drivers containing pyrotechnic substance and provided with a means of attaching it to a support so that it can rotate

  1 kg total pyrotechnic substance, no report effect, each whistle (if any)    25 g and    50 g whistle composition per wheel

1.3G

<  1 kg total pyrotechnic substance, no report effect, each whistle (if any)    5 g and    10 g whistle composition per wheel

1.4G

Aerial wheel

Flying Saxon, UFOs, rising crown

Tubes containing propellant charges and sparks-, flame- and/or noise-producing pyrotechnic substances, the tubes being fixed to a supporting ring

> 200 g total pyrotechnic substance or > 60 g pyrotechnic substance per driver,

  3% flash composition as report effects, each whistle (if any)    25 g and    50 g whistle composition per wheel

1.3G

  200 g total pyrotechnic substance and

  60 g pyrotechnic substance per driver,

  3% flash composition as report effects, each whistle (if any)    5 g and    10 g whistle composition per wheel

1.4G

Selection pack

Display selection box, display selection pack, garden selection box, indoor selection box; assortment

A pack of more than one type each corresponding to one of the types of fireworks listed in this table

The most hazardous firework type determines the classification

 

Firecracker

Celebration cracker, celebration roll, string cracker

Assembly of tubes (paper or cardboard) linked by a pyrotechnic fuse, each tube intended to produce an aural effect

Each tube    140 mg of flash composition or    1 g black powder

1.4G

Banger

Salute, flash banger, lady cracker

Non-metallic tube containing report composition intended to produce an aural effect

> 2 g flash composition per item

1.1G

  2 g flash composition per item and

  10 g per inner packaging

1.3G

  1 g flash composition per item and

  10 g per inner packaging or    10 g black powder per item

1.4G

 

2.1.3.6 Classification documentation

2.1.3.6.1 A competent authority assigning an article or substance into class 1 should confirm with the applicant that classification in writing.

2.1.3.6.2 A competent authority classification document may be in any form and may consist of more than one page, provided pages are numbered consecutively. The document should have a unique reference.

2.1.3.6.3 The information provided shall be easy to identify, legible and durable.

2.1.3.6.4 Examples of the information that may be provided in the classification documents are as follows:

.1       the name of the competent authority and the provisions in national legislation under which it is granted its authority;

.2       the modal or national regulations for which the classification document is applicable;

.3       confirmation that the classification has been approved, made or agreed in accordance with the United Nations Recommendations on the Transport of Dangerous Goods or the relevant modal regulations;

.4       the name and address of the person in law to which the classification has been assigned and any company registration which uniquely identifies a company or other body corporate under national legislation;

.5       the name under which the explosives will be placed on the market or otherwise supplied for transport;

.6       the Proper Shipping Name, UN number, Class, Hazard Division and corresponding compatibility group of the explosives;

.7       where appropriate, the maximum net explosive mass of the package or article;

.8       the name, signature, stamp, seal or other identification of the person authorized by the competent authority to issue the classification document is clearly visible;

.9       where safety in transport or the hazard division is assessed as being dependent upon the packaging, the packaging mark or a description of the permitted:

        inner packagings

        intermediate packagings

        outer packagings

.10     the classification document states the part number, stock number or other identifying reference under which the explosives will be placed onto the market or otherwise supplied for transport;

.11     the name and address of the person in law who manufactured the explosives and any company registration which uniquely identifies a company or other body corporate under national legislation;

.12     any additional information regarding the applicable packing instruction and special packing provisions where appropriate;

.13     the basis for assigning the classification, i.e. whether on the basis of test results, default for fireworks, analogy with classified explosive, by definition from the Dangerous Goods List etc.;

.14     any special conditions or limitations that the competent authority has identified as relevant to the safety for transport of the explosives, the communication of the hazard and international transport; and

.15     the expiry date of the classification document is given where the competent authority considers one to be appropriate.

 

Chapter 2.2. Class 2 – Gases

2.2.0 Introductory note

“Toxic” has the same meaning as “poisonous”.


Êóïèòü ïîëíûé òåêñò äîêóìåíòà ìîæíî ïîñëå àâòîðèçàöèè

Çà äîïîëíèòåëüíîé èíôîðìàöèåé îáðàùàéòåñü â ÎÎÎ "Ïëàíåòà Îäåññà"
Òåë. +380 50-336-5436 email: rise3info@gmail.com

Home